Art

J-GLOBAL ID：200902283730150109   Reference number：08A0631745

Single-component CT Crystals Based on 1,4-Benzoquinone Derivatives and TEMPO Radical

1,4-ベンゾキノン誘導体とTEMPOラジカルをベースにする単一成分CT結晶

Author (4)： NOBUSAWA Mitsunori (Graduate School of Material Sci., Univ. of Hyogo) ,  AKUTSU Hiroki (Graduate School of Material Sci., Univ. of Hyogo) ,  YAMADA Jun-ichi (Graduate School of Material Sci., Univ. of Hyogo) ,  NAKATSUJI Shin'ichi (Graduate School of Material Sci., Univ. of Hyogo)
Material： Chemistry Letters  (Chem Lett)
Volume： 37  Issue： 7  Page： 788-789 (J-STAGE)  Publication year： 2008 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *charge transfer ,  radical ,  intermolecular interaction ,  steric effect ,  spin system ,  donor ,  oxidation-reduction potential ,  cyclic voltammetry ,  X-Ray Diffraction ,  molecular structure ,  crystal structure ,  antiferromagnetism ,  Curie-Weiss law ,  *spin-spin interaction ,  ferromagnetism ,  *quinone ,  *nitrogen heterocyclic compound ,  molecular crystal

JST classification (2)： Aromatic monocyclic phenols and polyphenols  (CF05090V) ,  Pyridines  (CF07095Q)

Substance index (6)： [[4,4′-(3,6-Dichloro-2,5-dioxo-1,4-phenylene)bis(2,2,6,6-tetramethylpiperidine)]-1,1′-diylbisoxy]radical ,  [[4,4′-(3,6-Dibromo-2,5-dioxo-1,4-phenylene)bis(2,2,6,6-tetramethylpiperidine)]-1,1′-diylbisoxy]radical ,  [[4,4′-(4,6-Dichloro-2,5-dioxo-1,3-phenylene)bis(2,2,6,6-tetramethylpiperidine)]-1,1′-diylbisoxy]radical ,  [[4,4′-(4,6-Dibromo-2,5-dioxo-1,3-phenylene)bis(2,2,6,6-tetramethylpiperidine)]-1,1′-diylbisoxy]radical ,  [4-(3,4,6-Trichloro-2,5-dioxophenoxy)-2,2,6,6-tetramethylpiperidinooxy]radical ,  [4-(3,4,6-Tribromo-2,5-dioxophenoxy)-2,2,6,6-tetramethylpiperidinooxy]radical

Reference (13)：

• 1) a) H. A. Bent, Chem. Rev. 1968, 68, 587.
•  b) Organic Charge-transfer Complexes, ed. by R. Foster, Academic Press, London, 1969.
•  c) The Donor-Acceptor Approach to Molecular Interactions, ed. by V. Gutmann, Plenum Press, New York, 1978.
• 2) a) M. Iwamatsu, T. Kominami, K. Ueda, T. Sugimoto, T. Adachi, H. Fujita, H. Yoshino, Y. Mizuno, K. Murata, M. Shiro, Inorg. Chem. 2000, 39, 3810.
•  b) H. Tanaka, Y. Okano, H. Kobayashi, W. Suzuki, A. Kobayashi, Science 2001, 291, 285.

Terms in the title (5)： ベンゾキノン誘導体 ,  TEMPO ,  ラジカル ,  CT ,  結晶