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J-GLOBAL ID：200902283994677610   Reference number：03A0235048

Enantioselective Aziridination and Amination Using p-Toluenesulfonyl Azide in the Presence of Ru(salen)(CO) Complex.

Ru(salen)(CO)錯体存在下,p-トルエンスルホニルアジドを使用するエナンチオ選択的アジリジン化及びアミノ化

Author (5)： OMURA K (Kyushu Univ.) ,  MURAKAMI M (Kyushu Univ.) ,  UCHIDA T (Kyushu Univ.) ,  IRIE R (Kyushu Univ.) ,  KATSUKI T (Kyushu Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 32  Issue： 4  Page： 354-355  Publication year： Apr. 05, 2003 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： stereospecific reaction ,...

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JST classification (2)： Aromatic monocyclic sulfonic acids,sulfinic acids,sulfenic acids  (CF05140B) ,  Nobel metal catalysts  (CB06122I)

Substance index (24)： Tosyl azide ,  Styrene ,  4-Nitrostyrene ,  4-Bromostyrene ,  4-Phenyl-1-buten-3-yne ,  2-Vinylnaphthalene ,  2-Phenyl-1,3-butadiene ,  α-Methylstyrene ,  1-Phenylcyclohexene ,  Indene ,  N,N′-(Cyclohexane-1β,2α-diyl)bis(2-hydroxy-2′-phenyl-1,1′-binaphthalene-3-methanimine) ,  (2S)-1-Tosyl-2-phenylaziridine ,  1-Tosyl-2-(4-bromophenyl)aziridine ,  1-Tosyl-2-(4-nitrophenyl)aziridine ,  1-Tosyl-2-(phenylethynyl)aziridine ,  1-Tosyl-2-(2-naphthyl)aziridine ,  1-(p-Tolylsulfonyl)-2-(1-phenylethenyl)aziridine ,  2-Ethyl-1H-indene ,  N-(2-Phenylallyl)-p-toluenesulfonamide ,  N-(3-Phenyl-2-cyclohexenyl)-p-toluenesulfonamide ,  N-[1-(1H-Indene-2-yl)ethyl]-p-toluenesulfonamide ,  (1aS,6aR)-1-Tosyl-1,1a,6,6a-tetrahydroindeno[1,2-b]azirine ,  4-(1-Cyclohexenyl)styrene ,  1-(p-Tolylsulfonyl)-2-[4-(1-cyclohexenyl)phenyl]aziridine

Reference (27)：

• 1) a) J. T. Groves and T. Takahashi, J. Am. Chem. Soc., 105, 2073 (1983).
•  b) D. Mansuy, J.-P. Mahy, A. Dcureault, G. Bedi, and P. Battioni, J. Chem. Soc., Chem. Commun., 1984, 1161.
• 2) a) M. M. Faul and D. A. Evans, in “Asymmetric Oxidation Reaction, Practical Approach in Chemistry,” ed. by T. Katsuki, Oxford University Press, Oxford (2001), Chap. 2.7.
•  b) E. N. Jacobsen, in “Comprehensive Asymmetric Catalysis II,” ed. by E. N. Jacobsen, A. Pfaltz, and H. Yamamoto, Springer, Berlin (1999), Chap. 17.
• 3) a) T.-S. Lai, H.-L. Kwong, C.-M. Che, and S.-M. Peng, Chem. Commun., 1997, 2373.

Terms in the title (6)： Ru ,  CO ,  錯体 ,  p-トルエンスルホニルアジド ,  アジリジン化 ,  アミノ化