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J-GLOBAL ID：200902285819178956   Reference number：07A0824580

Rh(I)-catalyzed conjugate addition of alkenylzirconocene chloride: stereoselective formation of carbocycles through cascade reaction

Rh(I)触媒を用いるアルケニルジルコノセンクロリドの共役付加 カスケード反応による炭素環化合物の立体選択的な生成

Author (5)： HANZAWA Yuji (Lab. of Organic Reaction Chemistry, Showa Pharmaceutical Univ., 3-3165 Higashi-tamagawagakuen, Machida, Tokyo ...) ,  TAKEBE Yoshitaka (Lab. of Organic Reaction Chemistry, Showa Pharmaceutical Univ., 3-3165 Higashi-tamagawagakuen, Machida, Tokyo ...) ,  SAITO Akio (Lab. of Organic Reaction Chemistry, Showa Pharmaceutical Univ., 3-3165 Higashi-tamagawagakuen, Machida, Tokyo ...) ,  KAKUUCHI Akito (Tokyo Univ. of Pharmacy and Life Sci., 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, JPN) ,  FUKAYA Haruhiko (Tokyo Univ. of Pharmacy and Life Sci., 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 48  Issue： 37  Page： 6471-6474  Publication year： Sep. 10, 2007 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *zirconium complex ,...
Semi thesaurus term： Aldol condensation

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JST classification (1)： 4A and 5A groups  (CE01070U)

Substance index (22)： (E)-1-Phenyl-2-octene-1,7-dione ,  Chloro[(E)-3,3-dimethyl-1-butenyl]bis(2,4-cyclopentadienyl) zirconium(IV) ,  (1S)-1-Methyl-2α-benzoyl-3β-[(E)-3,3-dimethyl-1-butenyl]cyclohexane-1α-ol ,  (1S)-1-Methyl-2α-acetyl-3β-[(E)-3,3-dimethyl-1-butenyl]cyclohexane-1α-ol ,  (1R)-2β-Hydroxy-2-methyl-6α-[(E)-3,3-dimethyl-1-butenyl]cyclohexane-1β-carboxylic acid ethyl ester ,  (1S)-1-Methyl-2α-(piperidinocarbonyl)-3β-[(E)-3,3-dimethyl-1-butenyl]cyclohexane-1α-ol ,  (1α)-2α-Benzoyl-3β-[(E)-3,3-dimethyl-1-butenyl]cyclohexanol ,  (1S)-1-Methyl-2α-benzoyl-3β-[(E)-3,3-dimethyl-1-butenyl]cyclopentane-1α-ol ,  (1S)-1-Methyl-2α-acetyl-3β-[(E)-3,3-dimethyl-1-butenyl]cyclopentane-1α-ol ,  (1R)-2β-Hydroxy-2-methyl-5α-[(E)-3,3-dimethyl-1-butenyl]cyclopentane-1β-carboxylic acid ethyl ester ,  (1R,5S,7S)-4-[(E)-7-Oxo-2-octenoyl]-10,10-dimethyl-3-thia-4-azatricyclo[5.2.1.0^1,5]decane3,3-dioxide ,  (1R,5S,7S)-4-[[(1R)-2β-Hydroxy-2-methyl-6α-[(E)-3,3-dimethyl-1-butenyl]cyclohexane-1β-yl]carbonyl]-10,10-dimethyl-3-thia-4-azatricyclo[5.2.1.0^1,5]decane3,3-dioxide ,  (2E,7E)-1,9-Diphenyl-2,7-nonadiene-1,9-dione ,  α-[(1S)-2α-Benzoyl-3β-[(E)-3,3-dimethyl-1-butenyl]cyclohexane-1β-yl]acetophenone ,  α-[(1S)-2α-Benzoyl-3β-[(E)-1-hexenyl]cyclohexane-1β-yl]acetophenone ,  α-[(1S)-2α-Benzoyl-3β-[(E)-styryl]cyclohexane-1β-yl]acetophenone ,  α-[(3S)-4α-Benzoyl-5β-[(E)-3,3-dimethyl-1-butenyl]tetrahydro-2H-pyran-3β-yl]acetophenone ,  α-[(3S)-4α-Benzoyl-5β-[(E)-styryl]tetrahydro-2H-pyran-3β-yl]acetophenone ,  (3R)-3α-[(E)-3,3-Dimethyl-1-butenyl]-4β-benzoyl-5α-(β-oxophenethyl)cyclohexane-1,1-dicarboxylic acid diethyl ester ,  α-[(3S)-1-Tosyl-4α-benzoyl-5β-[(E)-3,3-dimethyl-1-butenyl]piperidine-3β-yl]acetophenone ,  α-[(1S)-2α-Benzoyl-3β-[(E)-3,3-dimethyl-1-butenyl]cyclopentane-1β-yl]acetophenone ,  α-[(1S)-2α-Benzoyl-3β-[(E)-styryl]cyclopentane-1β-yl]acetophenone

Terms in the title (6)： Rh ,  触媒 ,  共役付加 ,  カスケード反応 ,  炭素環 ,  立体