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J-GLOBAL ID：200902286455399915   Reference number：03A0528131

Asymmetric Induction of Three Consecutive Chiral Centers by Reactions of N-Enoylthioamides with Aldehydes.

N-エノイルチオアミド類とアルデヒドとの反応による3個の連続したキラル中心の不斉誘導

Author (8)： KATAOKA T (Gifu Pharmaceutical Univ., Gifu, JPN) ,  KINOSHITA H (Gifu Pharmaceutical Univ., Gifu, JPN) ,  KINOSHITA S (Gifu Pharmaceutical Univ., Gifu, JPN) ,  OSAMURA T (Gifu Pharmaceutical Univ., Gifu, JPN) ,  WATANABE S (Gifu Pharmaceutical Univ., Gifu, JPN) ,  IWAMURA T (Gifu Pharmaceutical Univ., Gifu, JPN) ,  MURAOKA O (Kinki Univ., Higashi-Osaka, JPN) ,  TANABE G (Kinki Univ., Higashi-Osaka, JPN)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 42  Issue： 25  Page： 2889-2891  Publication year： Jun. 30, 2003 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...
Semi thesaurus term： *Aldol condensation ,...

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JST classification (4)： Aromatic monocyclic aldehydes  (CF05160X) ,  Oxazoles,isoxazoles  (CF07080Y) ,  Thiazoles,isothiazoles  (CF07081P) ,  Eight or more-membered heterocyclic compounds  (CF07120T)

Substance index (16)： 4-Chlorobenzaldehyde ,  4-Nitrobenzaldehyde ,  4-Methylbenzaldehyde ,  Benzaldehyde ,  3-Nitrobenzaldehyde ,  3-Cinnamoylthiazolidine-2-thione ,  (E)-1-[(4S)-2-Thioxo-4-isopropyl-3-thiazolidinyl]-3-phenyl-2-propene-1-one ,  (1R,7R,8R,11S)-8-Phenyl-11-(4-chlorophenyl)-10-oxa-2,9-dithia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one ,  (1R,4S,7R,8S,11R)-4-Isopropyl-8-(4-chlorophenyl)-11-phenyl-9-oxa-2,10-dithia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one ,  (1R,4S,7R,8S,11R)-4-Isopropyl-8-(4-nitrophenyl)-11-phenyl-9-oxa-2,10-dithia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one ,  3-Cinnamoyl-4β-methyl-5β-phenyloxazolidine-2-thione ,  (1R,3R,4S,7R,8R,11R)-3,8-Diphenyl-4-methyl-11-(4-chlorophenyl)-2,10-dioxa-9-thia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one ,  (1R,3R,4S,7R,8R,11R)-3,11-Diphenyl-8-(4-nitrophenyl)-4-methyl-9-oxa-2-oxa-10-thia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one ,  (1R,3R,4S,7R,8R,11R)-3,11-Diphenyl-8-(3-nitrophenyl)-4-methyl-9-oxa-2-oxa-10-thia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one ,  (1R,3R,4S,7R,8R,11R)-3,8,11-Triphenyl-4-methyl-9-oxa-2-oxa-10-thia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one ,  (1R,3R,4S,7R,8R,11R)-3,11-Diphenyl-8-(4-methylphenyl)-4-methyl-9-oxa-2-oxa-10-thia-5-azatricyclo[5.2.2.0^1,5]undecane-6-one

Terms in the title (3)： アルデヒド ,  キラル中心 ,  不斉誘導