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J-GLOBAL ID：200902286942183138   Reference number：04A0034425

SYNTHESIS OF OPTICALLY ACTIVE TETRAHYDRO-3-BENZAZEPINE-2-CARBOXYLIC ACID DERIVATIVES VIA THE RING EXPANSION REACTION OF ISOQUINOLINES AND ENZYMATIC RESOLUTION

イソキノリン類の環拡大反応と酵素的分割を経由する光学活性なテトラヒドロ-3-ベンゾアゼピン-2-カルボン酸誘導体の合成

Author (7)： KOSEKI Y (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  OZAWA H (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  KITAHARA K (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  KATO I (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  SATO H (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  FUKAYA H (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN) ,  NAGASAKA T (Tokyo Univ. Pharmacy and Life Sci., Tokyo, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 63  Issue： 1  Page： 17-22  Publication year： Jan. 01, 2004 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...

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JST classification (3)： Seven-membered heterocyclic compounds  (CF07110I) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Applications of enzymes  (EB09100B)

Substance index (10)： Triethylamine ,  Pyridine ,  Acetic acid vinyl ester ,  1,5,6,10b-Tetrahydro-8,9-dimethoxy-10b-(hydroxymethyl)oxazolo[4,3-a]isoquinoline-3-one ,  8,9-Dimethoxy-10b-(α-hydroxybenzyl)-1,5,6,10b-tetrahydrooxazolo[4,3-a]isoquinoline-3-one ,  9,10-Dihydro-6,7-dimethoxy-1H,3H-2-oxa-10a-azabenzo[f]azulene-1-one ,  4-Phenyl-6,7-dimethoxy-9,10-dihydro-1H-2-oxa-10a-azabenzo[f]azulene-1(3H)-one ,  2-(Hydroxymethyl)-7,8-dimethoxy-2,3,4,5-tetrahydro-1H-3-benzazepine-3-carboxylic acid benzyl ester ,  (2S)-2-(Hydroxymethyl)-7,8-dimethoxy-2,3,4,5-tetrahydro-1H-3-benzazepine-3-carboxylic acid benzyl ester ,  (2S)-7,8-Dimethoxy-2,3,4,5-tetrahydro-1H-3-benzazepine-2-carboxylic acid

Terms in the title (6)： イソキノリン類 ,  環拡大反応 ,  酵素的分割 ,  光学活性 ,  カルボン酸 ,  誘導体