Art

J-GLOBAL ID：200902287072861840   Reference number：03A0202516

Transfer hydrogenation of a variety of ketones catalyzed by rhodium complexes in aqueous solution and their application to asymmetric reduction using chiral Schiff base ligands.

水溶液中におけるロジウム錯体を触媒とした各種ケトン類の移動水素化及びキラルSchiff塩基配位子を用いた不斉還元への応用

Author (5)： HIMEDA Y (National Inst. Advanced Industrial Sci. and Technol., Ibaraki, JPN) ,  ONOZAWA-KOMATSUZAKI N (National Inst. Advanced Industrial Sci. and Technol., Ibaraki, JPN) ,  SUGIHARA H (National Inst. Advanced Industrial Sci. and Technol., Ibaraki, JPN) ,  ARAKAWA H (National Inst. Advanced Industrial Sci. and Technol., Ibaraki, JPN) ,  KASUGA K (National Inst. Advanced Industrial Sci. and Technol., Ibaraki, JPN)
Material： Journal of Molecular Catalysis A: Chemical  (J Mol Catal A Chem)
Volume： 195  Issue： 1/2  Page： 95-100  Publication year： Mar. 18, 2003 
JST Material Number： B0605C  ISSN： 1381-1169  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Thesaurus term： *rhodium complex ,...
Semi thesaurus term： catalytic hydrogenation

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JST classification (3)： Nobel metal catalysts  (CB06122I) ,  Platinum family element complexes  (CE01100E) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (26)： 2,2'-Dipyridyl ,  Pentamethylcyclopentadiene ,  Acetone ,  Cyclohexanone ,  Pyruvic acid ethyl ,  2-Heptanone ,  2-Octanone ,  Acetophenone ,  2'-Chloroacetophenone ,  3'-Chloroacetophenone ,  4'-Chloroacetophenone ,  2'-Bromoacetophenone ,  4'-Bromoacetophenone ,  2'-Methoxyacetophenone ,  3'-Methoxyacetophenone ,  4'-Methoxyacetophenone ,  4'-Methylacetophenone ,  Propiophenone ,  2,2-Dimethylcyclohexanone ,  4-Phenyl-2-butanone ,  6-Methyl-5-hepten-2-one ,  5,6,7,8-Tetrahydro-2-(2-pyridyl)-6,6-dimethyl-5α,7α-methanoquinoline ,  (S)-4-Isopropyl-2-(2-pyridyl)-2-oxazoline ,  N-[(1R)-1-Phenylethyl]-1-(2-pyridyl)ethanimine ,  N-[(1R)-1-Phenylethyl](2-pyridyl)methanimine ,  (R)-1-Phenyl-N-(2-pyridylmethyl)ethanamine

Terms in the title (9)： 水溶液 ,  ロジウム錯体 ,  触媒 ,  ケトン類 ,  移動水素化 ,  キラル ,  Schiff塩基配位子 ,  不斉還元 ,  応用