Art

J-GLOBAL ID：200902288400001265   Reference number：03A0823030

New exo/endo selectivity observed in monohydrolysis of dialkyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylates.

ビシクロ[2.2.1]ヘプタ-5-エン-2,3-ジカルボン酸ジアルキルのモノ加水分解反応で観察された新規なexo/endo選択性

Author (2)： NIWAYAMA S (Oklahoma State Univ., OK, USA) ,  HIRAGA Y (Oklahoma State Univ., OK, USA)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 44  Issue： 47  Page： 8567-8570  Publication year： Nov. 17, 2003 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *Hydrolysis ,...
Semi thesaurus term： *bridged compound

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JST classification (2)： Stereochemistry of organic reaction  (CF02130V) ,  Bridged bicyclic carbocyclic compounds  (CF06100Q)

Substance index (14)： (1β,4β)-Norborna-5-ene-2β,3β-dicarboxylic acid dimethyl ester ,  (1β,4β)-Norborna-5-ene-2β,3β-dicarboxylic acid diethyl ester ,  (1β,4β)-Norborna-5-ene-2α,3α-dicarboxylic acid dimethyl ester ,  (1β,4β)-Bicyclo[2.2.1]hept-5-ene-2α,3α-dicarboxylic acid diethyl ester ,  (1R,2R,3R,4S)-Norborna-5-ene-2,3-dicarboxylic acid dimethyl ester ,  (1S,4R)-Norborna-2-ene-5β,6α-dicarboxylic acid diethyl ester ,  (1S,4R)-Bicyclo[2.2.1]hept-5-ene-2α,3α-dicarboxylic acid 2-methyl ester ,  (1α,4α)-Norborna-5-ene-2α,3α-dicarboxylic acid 2-ethyl ester ,  (1α,4α)-Bicyclo[2.2.1]hepta-5-ene-2β,3β-dicarboxylic acid 2-methyl ester ,  (1α,4α)-Norborna-5-ene-2β,3β-dicarboxylic acid 2-ethyl ester ,  (1β,4β)-Bicyclo[2.2.1]hepta-5-ene-2β,3α-dicarboxylic acid 3-methyl ester ,  (1α,4α)-Bicyclo[2.2.1]hepta-5-ene-2β,3α-dicarboxylic acid 2-ethyl ester ,  (1β,4β)-Bicyclo[2.2.1]hepta-5-ene-2β,3α-dicarboxylic acid 2-methyl ester ,  (1β,4β)-Bicyclo[2.2.1]hepta-5-ene-2β,3α-dicarboxylic acid 2-ethyl ester

Terms in the title (4)： ジカルボン酸 ,  加水分解反応 ,  観察 ,  選択性