Art

J-GLOBAL ID：200902289870217449   Reference number：03A0336741

Unusual α-glycosylation with galactosyl donors with a C2 ester capable of neighboring group participation.

隣接基関与が可能なC2エステルを持つガラクトシル供与体による異常なα-グリコシル化

Author (2)： CHEN L (Res. Center for Eco-Environmental Sci., Acad. Sinica, Beijing, CHN) ,  KONG F (Res. Center for Eco-Environmental Sci., Acad. Sinica, Beijing, CHN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 44  Issue： 18  Page： 3691-3695  Publication year： Apr. 28, 2003 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *glycosylation ,...

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JST classification (2)： Glycosides  (CF10057O) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (46)： 2-O,3-O,4-O,6-O-Tetrabenzoyl-α-D-galactopyranose trichloroacetimidate ,  1-O-(4-Methoxyphenyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O,4-O,6-O-tetrabenzoyl-β-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-(Isopropylthio)-1-deoxy-β-D-galactopyranose 2,3,4,6-tetraacetate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O,4-O,6-O-tetraacetyl-β-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  2,3,4,6-Tetra-O-acetyl-1-O-trichloroacetimidoyl-α-D-galactopyranose ,  1-(Isopropylthio)-6-O-allyl-1-deoxy-β-D-galactopyranose 2,3,4-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O,4-O-tribenzoyl-6-O-allyl-α-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O,4-O-tribenzoyl-6-O-allyl-β-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-(Isopropylthio)-4-O-allyl-1-deoxy-β-D-galactopyranose 2,3,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O,6-O-tribenzoyl-4-O-allyl-α-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O,6-O-tribenzoyl-4-O-allyl-β-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-(Isopropylthio)-4-O,6-O-benzylidene-1-deoxy-β-D-galactopyranose 2,3-dibenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O-dibenzoyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-(Isopropylthio)-4-O,6-O-benzylidene-1-deoxy-β-D-galactopyranose 2-benzoate 3-(chloroacetate) ,  1-O-(4-Methoxyphenyl)-4-O-[2-O-benzoyl-3-O-(chloroacetyl)-4-O,6-O-benzylidene-α-D-galactopyranosyl]-β-D-glucopyranose 2,3,6-tribenzoate ,  1-(Isopropylthio)-3-O-allyl-4-O,6-O-benzylidene-1-deoxy-β-D-galactopyranose 2-benzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-Dodecanol ,  1-O-Dodecyl-3-O-allyl-4-O,6-O-benzylidene-β-D-galactopyranose 2-benzoate ,  Cholesterol ,  1-O-(3β-Cholesteryl)-3-O-allyl-4-O,6-O-benzylidene-β-D-galactopyranose 2-benzoate ,  1-O-Methyl-α-D-glucopyranose 2,3,4-tribenzoate ,  1-O-Methyl-6-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-β-D-galactopyranosyl)-α-D-glucopyranose 2,3,4-tribenzoate ,  1-O-Methyl-α-D-mannopyranose 2,3,4-tribenzoate ,  1-O-Methyl-6-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-β-D-galactopyranosyl)-α-D-mannopyranose 2,3,4-tribenzoate ,  1-O-Methyl-β-D-xylopyranose 2,3-dibenzoate ,  1-O-Methyl-4-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-xylopyranose 2,3-dibenzoate ,  1-O-(4-Methoxyphenyl)-β-D-galactopyranose 2,3,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-galactopyranose 2,3,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-2-(trichloroacetylamino)-2-deoxy-β-D-glucopyranose 3,6-dibenzoate ,  1-O-(4-Methoxyphenyl)-2-(trichloroacetylamino)-4-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-2-deoxy-β-D-glucopyranose 3,6-dibenzoate ,  1-O-Allyl-2-O,3-O-dibenzoyl-β-D-glucopyranuronic acid methyl ester ,  1-O-Allyl-2-O,3-O-dibenzoyl-4-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-glucopyranuronic acid methyl ester ,  1-O-(4-Methoxyphenyl)-α-D-mannopyranose 2,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-3-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-α-D-mannopyranose 2,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-β-D-galactopyranose 2,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-3-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-galactopyranose 2,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-β-D-glucopyranose 2,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-3-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-glucopyranose 2,4,6-tribenzoate ,  1-O-Allyl-α-D-mannopyranose 3,4,6-tribenzoate ,  1-O-Allyl-2-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-α-D-mannopyranose 3,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-β-D-galactopyranose 3,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-2-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-glucopyranose 3,4,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-(2-O,3-O,6-O-tribenzoyl-β-D-galactopyranosyl)-β-D-glucopyranose 2,3,6-tribenzoate ,  1-O-(4-Methoxyphenyl)-4-O-[2-O,3-O,6-O-tribenzoyl-4-O-(2-O-benzoyl-3-O-allyl-4-O,6-O-benzylidene-α-D-galactopyranosyl)-β-D-galactopyranosyl]-β-D-glucopyranose 2,3,6-tribenzoate

Terms in the title (5)： 隣接基関与 ,  C2 ,  エステル ,  供与体 ,  グリコシル化