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J-GLOBAL ID：200902291845605986   Reference number：03A0443632

Kinetic Resolution of Optically Pure 3-Alkanol by Pseudomonas cepacia Lipase-Catalyzed Transesterification with Vinyl Acetate in Organic Solvent

有機溶媒中でPseudomonas cepaciaリパーゼ触媒を用いて酢酸ビニルとのエステル交換による光学的に純粋な3-アルカノールの速度論的分割

Author (7)： HIRATA H (Hokkaido Tokai Univ., Sapporo, JPN) ,  IKUSHIMA M (Hokkaido Tokai Univ., Sapporo, JPN) ,  WATANABE M (Hokkaido Tokai Univ., Sapporo, JPN) ,  KAWAUCHI K (Hokkaido Tokai Univ., Sapporo, JPN) ,  MIYAGISHI M (Hokkaido Tokai Univ., Sapporo, JPN) ,  CHEN Y-G (Hokkaido Tokai Univ., Sapporo, JPN) ,  YANAGISHITA H (National Inst. of Advanced Industrial Sci. and Technol., Tsukuba, JPN)
Material： Journal of Oleo Science  (J Oleo Sci)
Volume： 52  Issue： 7  Page： 375-386  Publication year： Jul. 01, 2003 
JST Material Number： G0238A  ISSN： 1345-8957  CODEN： JOSOAP  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： Pseudomonas cepacia ,...

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JST classification (1)： Aliphatic alcohols  (CF03090H)

Substance index (3)： 1,2-Dichloroethane ,  Acetonitrile ,  Hexane

Reference (21)：

• 1. Y.-F. WANG and C.-H. WONG, Lipase-catalyzed Irreversible Transesterification for Preparative Synthesis of Chiral Glycerol Derivatives, J. Org. Chem., Vol. 53, 3127-3129 (1988).
• 2. J. HIRATAKAE, M. INAGAKI, T. NISHIOKA and J. ODA, Irreversible and Highly Enantioselective Acylation of 2-Halo-1-arylethanols in Organic Solvents Catalyzed by a Lipase from Pseudomonas fluorescens, J. Org. Chem., Vol. 53, 6130-6133 (1988).
• 3. Y.-F. WANG, J.J. LALONDE, M. MOMONGAN, D.E. BERGBREITER and C.-H. WONG, Lipase-catalyzed Irreversible Transesterification using Enol Esters as Acylating Reagents: Preparative Enantio- and Regioselective Syntheses of Alcohols, Glycerol Derivatives, Sugars, and Organometallics, J. Am. Chem. Soc., Vol. 110, 7200-7205 (1988).
• 4. M.D. CASTING, B.D. JESO, S. DRAULLARD and M. MALLIARD, Enzymatic Reactions in Organic Synthesis: 2. Ester Interchange of Vinyl Esers, Tetrahedron Lett., Vol. 28, 953-954 (1987).
• 5. C.-S. CHEN and Y.-C. LIU, Stereochemical Recognition in Lipase Catalysis, Yukagaku, Vol. 41, 724-733 (1992).

Terms in the title (9)： 有機溶媒 ,  Pseudomonas ,  リパーゼ ,  触媒 ,  酢酸ビニル ,  エステル交換 ,  光学 ,  アルカノール ,  速度論的分割