Art

J-GLOBAL ID：200902293290308258   Reference number：03A0305097

New total synthesis of (+)-cystothiazole A based on palladium-catalyzed cyclization-methoxycarbonylation.

パラジウム触媒による環化-メトキシカルボニル化に基づく(+)-シストチアゾールAの新規な全合成

Author (4)： KATO K (Toho Univ., Chiba, JPN) ,  SASAKI T (Toho Univ., Chiba, JPN) ,  TAKAYAMA H (Toho Univ., Chiba, JPN) ,  AKITA H (Toho Univ., Chiba, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 59  Issue： 15  Page： 2679-2685  Publication year： Apr. 07, 2003 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： palladium catalyst ,...
Semi thesaurus term： Wittig reaction ,...

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JST classification (2)： Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P) ,  Basic research of antifungal drugs  (GW17060K)

Substance index (14)： Cystothiazole A ,  p-Benzoquinone ,  (4R,5R,E)-3,5-Dimethoxy-4-methyl-6-oxo-2-hexenoic acid methyl ester ,  2′-Isopropyl-4-(triphenylphosphoniomethyl)-2,4′-bithiazole ,  [(2E)-3α-Methyl-4β-hydroxytetrahydrofuran-2-ylidene]acetic acid methyl ester ,  (2R,3S)-3-Methyl-4-pentyne-1,2-diol ,  (2R,3S)-2,3-Epoxybutanoic acid methyl ester ,  [(2E,3R)-3α-Methyl-4β-methoxytetrahydrofuran-2-ylidene]acetic acid methyl ester ,  [(2Z,3R)-3α-Methyl-4β-methoxytetrahydrofuran-2-ylidene]acetic acid methyl ester ,  (3R,4R)-2-Hydroxy-3-methyl-4-methoxytetrahydrofuran-2-acetic acid methyl ester ,  (4R,5R)-3-Oxo-4-methyl-5-methoxy-6-(tert-butyldimethylsiloxy)hexanoic acid methyl ester ,  2-Acetylthiazole-4-carboxylic acid methyl ester ,  (Z)-Cystothiazole A ,  (Trimethylsilyl)lithioamine

Terms in the title (4)： パラジウム触媒 ,  環化 ,  シストチアゾールA ,  全合成