Art

J-GLOBAL ID：200902293841346350   Reference number：06A0748756

Regioselective Reactions of 1-Alkylidene-2-oxyallyl Cations with Furan: Control of [4 + 3] Cycloaddition, [3 + 2] Cycloaddition, and Electrophilic Substitution

1-アルキリデン-2-オキシアリルカチオン類とフランとの位置選択的反応 [4+3]環状付加,[3+2]環状付加,及び求電子置換反応の制御

Author (5)： FUJITA Morifumi (Univ. Hyogo, Hyogo, JPN) ,  OSHIMA Makoto (Univ. Hyogo, Hyogo, JPN) ,  OKUNO Sakuro (Univ. Hyogo, Hyogo, JPN) ,  SUGIMURA Takashi (Univ. Hyogo, Hyogo, JPN) ,  OKUYAMA Tadashi (Univ. Hyogo, Hyogo, JPN)
Material： Organic Letters  (Org Lett)
Volume： 8  Issue： 18  Page： 4113-4116  Publication year： Aug. 31, 2006 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： oxygen heterocyclic compound ,...

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JST classification (2)： Regiochemistry of organic reaction  (CF02140G) ,  Cyclopropanes  (CF04020P)

Substance index (12)： Furan ,  1-Methoxy-1-(trimethylsiloxy)-2,2-dimethyl-3-cyclohexylidenecyclopropane ,  1,1-Bis(trimethylsiloxy)-2,2-dimethyl-3-cyclohexylidenecyclopropane ,  2-Cyclohexylidene-4,4-dimethyl-8-oxabicyclo[3.2.1]octa-6-ene-3-one ,  1,1-Dimethoxy-2,2-dimethyl-3-cyclohexylidenecyclopropane ,  2-(1-Cyclohexylidene-2-methoxy-3-methyl-2-butenyl)furan ,  2-(1-Cyclohexylidene-2-oxo-3-methylbutyl)furan ,  2-[1-(2-Furyl)cyclohexyl]-4-(2-oxoethyl)-5,5-dimethyl-2-cyclopentene-1-one ,  1-Chloro-1-cyclohexylidene-2-methoxy-3-methyl-2-butene ,  1-Chloro-1-cyclohexylidene-3-methyl-2-butanone ,  Benzofuran ,  1,1-Dimethyl-3-cyclohexylidene-2,3,3a,8b-tetrahydro-1H-cyclopenta[b]benzofuran-2-one

Terms in the title (4)： フラン ,  位置選択的反応 ,  環状付加 ,  求電子置換反応