Art

J-GLOBAL ID：200902294186168076   Reference number：07A0848652

(+)-Saxitoxin: A First and Second Generation Stereoselective Synthesis

(+)-サキシトキシン 第一および第二世代立体選択的合成

Author (3)： FLEMING James J. (Stanford Univ., California) ,  MCREYNOLDS Matthew D. (Stanford Univ., California) ,  DU BOIS J. (Stanford Univ., California)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 129  Issue： 32  Page： 9964-9975  Publication year： Aug. 15, 2007 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： total synthesis ,...
Semi thesaurus term： *saxitoxin ,...

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JST classification (1)： Other natural substances of biological origin  (CF10090R)

Substance index (15)： (+)-Saxitoxin ,  Sulfamic acid [(4S)-2,2-dimethyl-1,3-dioxolane-4α-yl]methyl ester ,  (3aα,7aα)-2,2-Dimethyl-1,3,6-trioxa-4-aza-5-thiahydrindane 5,5-dioxide ,  (4R)-4α-[4-(Tosyloxy)-1-butynyl]-1-oxa-2-thia-3-azacyclohexane-5α-ol 2,2-dioxide ,  (4R)-3-(4-Methoxybenzyl)-4α-[4-[methylthio(4-methoxyphenylsulfonylimino)methylamino]-1-butenyl]-5α-hydroxytetrahydro-1,2,3-oxathiazine 2,2-dioxide ,  (4R)-4α-[4-[Methylthio(4-methoxyphenylsulfonylimino)methylamino]-1-butenyl]-5β-azidotetrahydro-1,2,3-oxathiazine 2,2-dioxide ,  (2R,3R)-2-Azido-3-[2-(4-methoxyphenylsulfonyl)guanidino]-7-[methylthio(4-methoxyphenylsulfonylimino)methylamino]-4-heptene-1-ol ,  (2R,3R)-2-Amino-3-[2-(4-methoxyphenylsulfonyl)guanidino]-7-[methylthio(4-methoxyphenylsulfonylimino)methylamino]-4-heptene-1-ol ,  (4R)-2-(4-Methoxyphenylsulfonylimino)-5α-[2-(4-methoxyphenylsulfonyl)guanidino]-2,3,4,5,8,9-hexahydro-1H-1,3-diazonine-4β-methanol ,  (3R)-1-(4-Methoxyphenylsulfonylimino)-3β-(tert-butyldimethylsiloxymethyl)-4α-[2-(4-methoxyphenylsulfonyl)guanidino]octahydropyrrolo[1,2-c]pyrimidine-4aα,5β-diol ,  (4R)-2-(4-Methoxyphenylsulfonylimino)-4β-(carbamoyloxymethyl)-5α-[2-(4-methoxyphenylsulfonyl)guanidino]-2,3,4,5,8,9-hexahydro-1H-1,3-diazonine ,  (3R)-1-(4-Methoxyphenylsulfonylimino)-3β-(carbamoyloxymethyl)-4α-[2-(4-methoxyphenylsulfonyl)guanidino]octahydropyrrolo[1,2-c]pyrimidine-4aα,5β-diol ,  N-Boc-L-Serine methyl ester ,  (2R)-N-(4-Methoxybenzyl)-2-(tert-butoxycarbonylamino)-3-(tert-butyldiphenylsiloxy)propane-1-imine N-oxide ,  N-(4-Methoxybenzyl)-N-[(1R)-1-[(R)-1-(benzyloxycarbonylamino)-2-(tert-butyldiphenylsiloxy)ethyl]-5-[methylthio(4-methoxyphenylsulfonylimino)methylamino]-2-pentynyl]hydroxylamine

Terms in the title (3)： サキシトキシン ,  世代 ,  立体選択的合成