Art

J-GLOBAL ID：200902295168861747   Reference number：07A0778087

The intramolecular tandem Michael/Mannich-type reaction of α,β-unsaturated carbonyl compounds with acyliminium ions provides access to chiral indolizidines

キラルインドリジジン類にアクセスするのに必要なアシルイミニウムイオンを用いたα,β-不飽和カルボニル化合物の分子内タンデムMichael/Mannich-型反応

Author (5)： KOSEKI Yuji (Tokyo Univ. of Pharmacy and Life Sciences, School of Pharmacy, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, JPN) ,  FUJINO Koji (Tokyo Univ. of Pharmacy and Life Sciences, School of Pharmacy, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, JPN) ,  TAKESHITA Ai (Tokyo Univ. of Pharmacy and Life Sciences, School of Pharmacy, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, JPN) ,  SATO Hiroto (Tokyo Univ. of Pharmacy and Life Sciences, School of Pharmacy, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, JPN) ,  NAGASAKA Tatsuo (Tokyo Univ. of Pharmacy and Life Sciences, School of Pharmacy, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, JPN)
Material： Tetrahedron: Asymmetry  (Tetrahedron Asym)
Volume： 18  Issue： 13  Page： 1533-1539  Publication year： Jul. 17, 2007 
JST Material Number： T0907A  ISSN： 0957-4166  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...
Semi thesaurus term： *Mannich-type reaction ,...

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JST classification (2)： Alkaloids  (CF10030D) ,  Other condensed derivatives of pyridine  (CF07097Y)

Substance index (7)： 3-[(E)-5-(2-Ethoxy-5-oxopyrrolizino)-2-pentenoyl]-4β-phenyloxazolidine-2-one ,  (4S)-3-[(E)-5-(2-Ethoxy-5-oxopyrrolizino)-2-pentenoyl]-4β-benzyloxazolidine-2-one ,  (7S)-7α-Iodo-8β-[[(4S)-2-oxo-4β-phenyl-3-oxazolidinyl]carbonyl]-1,5,6,7,8,8aβ-hexahydroindolizine-3(2H)-one ,  (8aα)-8β-[(2-Oxo-4β-phenyloxazolidine-3-yl)carbonyl]-7α-iodooctahydroindolizine-3-one ,  (8aα)-8α-[(2-Oxo-4β-phenyloxazolidine-3-yl)carbonyl]-7β-iodooctahydroindolizine-3-one ,  (7S)-7α-Iodo-8β-[[(4S)-2-oxo-4β-benzyl-3-oxazolidinyl]carbonyl]-1,5,6,7,8,8aβ-hexahydroindolizine-3(2H)-one ,  (7S)-7α-Iodo-8β-[[(4S)-2-oxo-4β-benzyl-3-oxazolidinyl]carbonyl]-1,5,6,7,8,8aα-hexahydroindolizine-3(2H)-one

Terms in the title (7)： キラル ,  インドリジジン類 ,  アクセス ,  不飽和 ,  カルボニル化合物 ,  タンデム ,  型