Art

J-GLOBAL ID：200902296358228427   Reference number：05A0748963

Highly regio- and stereo-selective carbometallation reaction of fluorine-containing internal acetylenes with organocopper reagents

内部にふっ素を含有するアセチレン類と有機銅試薬の高度な位置及び立体選択的カルボメタル化反応

Author (6)： KONNO Tsutomu (Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN) ,  DAITOH Takeshi (Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN) ,  NOIRI Atsushi (Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN) ,  CHAE Jungha (Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN) ,  ISHIHARA Takashi (Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN) ,  YAMANAKA Hiroki (Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 61  Issue： 39  Page： 9391-9404  Publication year： Sep. 26, 2005 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： metalation ,...
Semi thesaurus term： ふっ素化アルキン ,...

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JST classification (3)： Alkynes  (CF03040E) ,  Stereochemistry of organic reaction  (CF02130V) ,  Basic research of drugs acting on endocrine system and reproductive organ  (GW10010K)

Substance index (22)： Butyl lithium ,  Diethyl zinc ,  Phenylboronic acid ,  (Z)-1,1,1-Trifluoro-3-(4-chlorophenyl)-2-heptene ,  (2Z)-1,1,1-Trifluoro-3-(4-chlorophenyl)-2-butene ,  (1Z)-1-(4-Chlorophenyl)-1-phenyl-3,3,3-trifluoro-1-propene ,  (2Z)-1,1,1-Trifluoro-3-(2-methoxyphenyl)-2-heptene ,  4-(Trifluoro-1-propynyl)phenyl chloride ,  (4Z)-4-(Trifluoromethyl)-5-(4-chlorophenyl)-1,4-nonadiene ,  (4Z)-2-Methylene-4-(trifluoromethyl)-5-(4-chlorophenyl)-4-nonenoic acid methyl ester ,  (2E)-1,1,1-Trifluoro-2-iodo-3-(4-chlorophenyl)-2-heptene ,  (2Z)-1,1,1-Trifluoro-2-phenyl-3-(4-chlorophenyl)-2-heptene ,  (3Z)-1-(Trimethylsilyl)-3-(trifluoromethyl)-4-(4-chlorophenyl)-3-octene-1-yne ,  (2Z)-1,1,1-Trifluoro-3-(3-chlorophenyl)-2-heptene ,  (2Z)-1,1,1-Trifluoro-3-(4-methoxybenzyl)-2-heptene ,  (2Z)-1,1,1-Trifluoro-3-(4-chlorophenyl)-2-pentene ,  (4Z)-4-(4-Chlorophenyl)-6,6,6-trifluoro-4-hexenoic acid methyl ester ,  (4Z)-4-(4-Chlorophenyl)-6,6,6-trifluoro-4-hexenenitrile ,  Panomifene ,  3,3,3-Trifluoro-1-propynylbenzene ,  Dibutylcopper(II)・lithium ,  Dibutylcopper(II)・dilithium・carbonitrile

Terms in the title (6)： ふっ素 ,  アセチレン類 ,  銅 ,  試薬 ,  立体 ,  カルボメタル化