Art

J-GLOBAL ID：200902296465936728   Reference number：06A0608446

Sequencing of Three-Component Olefin Metatheses: Total Synthesis of Either (+)-Gigantecin or (+)-14-Deoxy-9-oxygigantecin

三成分オレフィンメタセシスの連鎖 (+)-ギガンテシンまたは(+)-14-デオキシ-9-オキシギガンテシンの全合成

Author (4)： HOYE Thomas R. (Univ. Minnesota, Minnesota) ,  EKLOV Brian M. (Univ. Minnesota, Minnesota) ,  JEON Junha (Univ. Minnesota, Minnesota) ,  KHOROOSI Mila (Univ. Minnesota, Minnesota)
Material： Organic Letters  (Org Lett)
Volume： 8  Issue： 15  Page： 3383-3386  Publication year： Jul. 20, 2006 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *Annonaceae ,...
Semi thesaurus term： metathesis

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=06A0608446&from=J-GLOBAL&jstjournalNo=W1171A") }}

JST classification (2)： Other natural substances of biological origin  (CF10090R) ,  Plant biochemistry  (EH01050J)

Substance index (8)： Gigantecin ,  (5S)-3-[(2R,7S)-2,7-Dihydroxy-7-[(2S)-5β-[(4R)-4-hydroxy-4-[(2R)-5α-[(1R)-1-hydroxytridecyl]oxolane-2β-yl]butyl]oxolane-2α-yl]heptyl]-5α-methyl-2,5-dihydrofuran-2-one ,  (4R,10S,13S,14S,17R,18R,21R,22R)-2-[(S)-2-Hydroxypropylidene]-4,22-bis(triisopropylsiloxy)-10,13:18,21-diepoxy-14,17-(diphenylsilanediylbisoxy)-7,15-tetratriacontadienoic acid lactone ,  (5S)-3-[(R)-2-(Triisopropylsiloxy)-5-hexenyl]-5α-methyl-2,5-dihydrofuran-2-one ,  (βR,2S)-β-Iodo-5β-allyltetrahydrofuran-2α-ethanol ,  (αS,2S)-α-Vinyl-5β-allyltetrahydrofuran-2α-methanol ,  (αR,2R)-α-Vinyl-5α-[(R)-1-(triisopropylsiloxy)tridecyl]tetrahydrofuran-2β-methanol ,  (4S,7S,8S,12R,13R,16R,17R)-8,12-Divinyl-10,10-diphenyl-17-(triisopropylsiloxy)-4,7:13,16-diepoxy-9,11-dioxa-10-sila-1-nonacosene

Terms in the title (3)： オレフィンメタセシス ,  連鎖 ,  全合成