Art

J-GLOBAL ID：200902297503788211   Reference number：03A0557196

Palladium-Catalyzed Asymmetric Arylation, Vinylation, and Allenylation of tert-Cyclobutanols via Enantioselective C-C Bond Cleavage.

エナンチオ選択的C-C結合開裂を経たtert-シクロブタノール類のパラジウム触媒による不斉アリール化,ビニル化,およびアレニル化

Author (4)： MATSUMURA S (Kyoto Univ., Kyoto, JPN) ,  MAEDA Y (Kyoto Univ., Kyoto, JPN) ,  NISHIMURA T (Kyoto Univ., Kyoto, JPN) ,  UEMURA S (Kyoto Univ., Kyoto, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 125  Issue： 29  Page： 8862-8869  Publication year： Jul. 23, 2003 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...
Semi thesaurus term： chirality

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JST classification (2)： Cyclobutanes  (CF04030A) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (58)： 2-(Diphenylphosphino)-2′-methoxy-1,1′-binaphthalene ,  1,1′-Binaphthalene-2-yldiphenylphosphine ,  [(R)-1-[2-(Diphenylphosphino)-2,4-cyclopentadienyl]ethyl]dimethylamine ,  1,3α-Diphenylcyclobutane-1α-ol ,  Phenyl trifluoromethanesulfonate ,  (S)-1,3,4-Triphenyl-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(2-methoxyphenyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(3-methoxyphenyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(4-methoxyphenyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(4-chlorophenyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(4-methylphenyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(4-tert-butylphenyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-[4-(dimethylamino)phenyl]-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(1-naphthyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(2-naphthyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(9-anthryl)-1-butanone ,  1-(Diphenylphosphino)-5-[(R)-1-(diethylamino)ethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-(dibenzylamino)ethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-morpholinoethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-pyrrolizinoethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-[methyl[(S)-α-methylbenzyl]amino]ethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-[methyl[(R)-α-methylbenzyl]amino]ethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-(methylcyclohexylamino)ethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-(methyl tert-butylamino)ethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-[methyl(1-adamantyl)amino]ethyl]-1,3-cyclopentadiene ,  1-(Diphenylphosphino)-5-[(R)-1-[methyl(2-adamantyl)amino]ethyl]-1,3-cyclopentadiene ,  1-Phenyl-3α-tert-butylcyclobutane-1α-ol ,  1-Phenyl-3α-hexylcyclobutane-1α-ol ,  1-Methyl-3α-phenylcyclobutane-1α-ol ,  1-Butyl-3α-phenylcyclobutane-1α-ol ,  1-tert-Butyl-3α-phenylcyclobutane-1α-ol ,  1-(1-Naphthyl)-3α-phenylcyclobutane-1α-ol ,  1-(2-Naphthyl)-3α-phenylcyclobutane-1α-ol ,  1,3α-Diphenyl-3-methylcyclobutane-1α-ol ,  1,3β-Diphenyl-3-methylcyclobutane-1α-ol ,  1-Butyl-3α-phenyl-3-methylcyclobutane-1α-ol ,  1-Butyl-3β-phenyl-3-methylcyclobutane-1α-ol ,  rel-(R^*)-1-Phenyl-3-benzyl-4,4-dimethyl-1-pentanone ,  rel-(R^*)-1-Phenyl-3-benzyl-1-nonanone ,  rel-(R^*)-4,5-Diphenyl-2-pentanone ,  (S)-1,2-Diphenyl-4-octanone ,  rel-(R^*)-2,2-Dimethyl-5,6-diphenyl-3-hexanone ,  rel-(R^*)-1-(1-Naphthyl)-3,4-diphenyl-1-butanone ,  rel-(R^*)-1-(2-Naphthyl)-3,4-diphenyl-1-butanone ,  (S)-1,3,4-Triphenyl-3-methyl-1-butanone ,  (S)-1,2-Diphenyl-2-methyl-4-octanone ,  1-(Trifluoromethylsulfonyloxy)-3,4-dihydronaphthalene ,  Cyclohexene-1-ol trifluoromethanesulfonate ,  1-Bromo-2-methyl-1-propene ,  Vinyl bromide ,  α-Bromostyrene ,  rel-(R^*)-1,3-Diphenyl-4-(3,4-dihydronaphthalene-1-yl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-4-(1-cyclohexenyl)-1-butanone ,  rel-(R^*)-1,3-Diphenyl-6-methyl-5-heptene-1-one ,  (S)-1,3-Diphenyl-5-hexene-1-one ,  rel-(R^*)-1,3,5-Triphenyl-5-hexene-1-one ,  1-Phenyl-3-acetoxy-3-methyl-1-butyne ,  rel-(R^*)-1,3,5-Triphenyl-7-methyl-5,6-octadiene-1-one

Terms in the title (8)： C-C結合 ,  開裂 ,  TERT ,  シクロブタノール ,  パラジウム触媒 ,  アリール化 ,  ビニル化 ,  アレニル化