Art

J-GLOBAL ID：200902298490806807   Reference number：08A0904356

Ortho-selective Arylation of Arylazoles with Aryl Bromides Catalyzed by Ruthenium Complexes

ルテニウム錯体を触媒に用いるアリールアゾール類のアリールブロミドによるオルト選択的アリール化

Author (4)： OI Shuichi (Dep. of Biomolecular Engineering, Graduate School of Engineering, Tohoku Univ.) ,  SASAMOTO Hiromi (Dep. of Biomolecular Engineering, Graduate School of Engineering, Tohoku Univ.) ,  FUNAYAMA Raito (Dep. of Biomolecular Engineering, Graduate School of Engineering, Tohoku Univ.) ,  INOUE Yoshio (Dep. of Biomolecular Engineering, Graduate School of Engineering, Tohoku Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 37  Issue： 9  Page： 994-995 (J-STAGE)  Publication year： 2008 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *ruthenium complex ,  *ruthenium catalyst ,  *arylation ,  catalytic reaction ,  selectivity ,  chloro complex ,  potassium carbonate ,  coupling reaction ,  regiospecific reaction ,  chemical synthesis ,  reaction path ,  addition reaction ,  *nitrogen heterocyclic compound ,  *sulfur heterocyclic compound ,  aromatic compound ,  organophosphorus compound ,  aromatic bromine compound ,  aromatic hydrocarbon

JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  Thiazoles,isothiazoles  (CF07081P)

Substance index (24)： 1-(1,1′:3′,1′′-Terbenzene-2′-yl)-1H-pyrazole ,  1-(1,1′-Biphenyl-2-yl)-1H-indazole ,  1-[2,6-Bis(3-thienyl)phenyl]-1H-pyrazole ,  1-Phenyl-1H-indazole ,  1-Phenyl-1H-pyrazole ,  2-(1,1′:3′,1′′-Terbenzene-2′-yl)thiazole ,  2-(1,1′-Biphenyl-2-yl)thiazole ,  2-(2-Methylphenyl)oxazole ,  2-(2-Methylphenyl)thiazole ,  2-(2-Methylphenyl)-2H-1,2,3-triazole ,  2-(3,2′-Dimethyl-1,1′-biphenyl-2-yl)thiazole ,  2-(3-Methyl-2-biphenylyl)oxazole ,  2-(3-Methyl-2-biphenylyl)thiazole ,  2-(3-Methyl-1,1′-biphenyl-2-yl)-2H-1,2,3-triazole ,  2-(3-Methyl-4′-methoxy-1,1′-biphenyl-2-yl)thiazole ,  2-[2-(2-Naphthyl)-6-methylphenyl]thiazole ,  2-Phenylthiazole ,  2-Bromonaphthalene ,  3-Bromothiophene ,  1-Bromo-4-methoxybenzene ,  Triphenylphosphine ,  Bromobenzene ,  1-Bromo-2-methylbenzene ,  Benzene

Reference (33)：

• 1) a) Cross-Coupling Reactions, ed. by N. Miyaura, Springer, Berlin, 2002.
•  b) Metal-Catalyzed Cross-Coupling Reactions, 2nd ed., ed. by A. de Meijere, F. Diederich, Wiley-VCH, Weinheim, 2004.
• 2) a) I. V. Seregin, V. Gevorgyan, Chem. Soc. Rev. 2007, 36, 1173.
•  b) D. Alberico, M. E. Scott, M. Lautens, Chem. Rev. 2007, 107, 174.
•  c) T. Satoh, M. Miura, Chem. Lett. 2007, 36, 200.

Terms in the title (3)： ルテニウム錯体 ,  触媒 ,  アリール化