Art

J-GLOBAL ID：200902298528936920   Reference number：08A0286123

Novel Oxidative Generation of Ammonium Ylides and the Subsequent Silicon Polonovski Reaction

アンモニウムイリド類の新しい酸化的生成と続くケイ素Polonovski反応

Author (4)： HONDA Kiyoshi (Graduate School of Engineering, Yokohama National Univ.) ,  SHIBUYA Hiromasa (Graduate School of Engineering, Yokohama National Univ.) ,  HOSHINO Yujiro (Graduate School of Environment and Information Sciences, Yokohama National Univ.) ,  INOUE Seiichi (Graduate School of Environment and Information Sciences, Yokohama National Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 37  Issue： 4  Page： 442-443 (J-STAGE)  Publication year： 2008 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *ammonium ylide ,  *rearrangement reaction ,  consecutive reaction ,  oxidation ,  reaction mechanism ,  reaction product ,  *organosilicon compound ,  reaction intermediate ,  Brook rearrangement ,  tandem reaction
Semi thesaurus term： *Polonovski反応

JST classification (2)： Rearrangement reaction,isomerization  (CF02070E) ,  Organosilicon compounds  (CF08030C)

Substance index (7)： N-Methyl-N-(tert-butyldimethylsilylcyanomethyl)-2-methyl-4-(benzyloxy)-1-butene-3-amine ,  N-Methyl-N-(tert-butyldimethylsilylmethyl)-2,6-dimethyl-8-(benzyloxy)-1,6-octadiene-3-amine ,  N-Methyl-N-(triisopropylsilylcyanomethyl)-2-methyl-4-(benzyloxy)-1-butene-3-amine ,  N-Methyl-N-(triethylsilylcyanomethyl)-2-methyl-4-(benzyloxy)-1-butene-3-amine ,  N-Methyl-N-(trimethylsilylcyanomethyl)-2-methyl-4-(benzyloxy)-1-butene-3-amine ,  N-Methyl-N-(trimethylsilylmethyl)-2,6-dimethyl-8-(benzyloxy)-1,6-octadiene-3-amine ,  N-Methyl-N-(trimethylsilylmethyl)-2-methyl-4-(benzyloxy)-1-butene-3-amine

Reference (18)：

• 1) a) M. Ikeda, Y. Tamura, J. Synth. Org. Chem. Jpn. 1980, 38, 10.
•  b) D. Grierson, Org. React. 1990, 39, 85.
• 2) a) R. Okazaki, N. Tokitoh, J. Chem. Soc., Chem. Commun. 1984, 192.
•  b) N. Tokitoh, R. Okazaki, Tetrahedron Lett. 1984, 25, 4677.
•  c) N. Tokitoh, R. Okazaki, Chem. Lett. 1984, 1937.

Terms in the title (3)： アンモニウムイリド ,  酸化 ,  ケイ素