Art

J-GLOBAL ID：200902299188355037   Reference number：03A0306352

Chemoenzymatic synthesis of [3,9-¹³C]-labeled NeuAc and KDN.

[3,9-¹³C]標識化NeuAc及びKDNの化学酵素的合成

Author (6)： SATO K (Kanagawa Univ., Yokohama, JPN) ,  AKAI S (Kanagawa Univ., Yokohama, JPN) ,  HIROSHIMA T (Kanagawa Univ., Yokohama, JPN) ,  AOKI H (Kanagawa Univ., Yokohama, JPN) ,  SAKUMA M (Kanagawa Univ., Yokohama, JPN) ,  SUZUKI K (Kanagawa Univ., Yokohama, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 44  Issue： 17  Page： 3513-3516  Publication year： Apr. 21, 2003 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *amino sugar ,...
Semi thesaurus term： ketoaldonic acid ,...

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JST classification (3)： Monosaccharides  (CF10052H) ,  Labeled compounds  (CB10050N) ,  Applications of enzymes  (EB09100B)

Substance index (29)： Methyl 2,3-O-(1-acetyl-2-methyl-1-azapropane-1,2-diyl)-5-O,6-O-isopropylidene-2-deoxy-α-D-mannofuranoside ,  2,2-Dimethoxypropane ,  Triphenylphosphine ,  Iodo(13C)methane ,  (¹³C)Methyltriphenylphosphonium・iodide ,  D-Mannose ,  2-O,3-O:5-O,6-O-Diisopropylidene-D-mannofuranose ,  Benzyl 2-O,3-O:5-O,6-O-diisopropylidene-α-D-mannofuranoside ,  Methyl 2,3-O-(1-acetyl-2-methyl-1-azapropane-1,2-diyl)-2-deoxy-α-D-mannofuranoside ,  Benzyl 2-O,3-O-isopropylidene-α-D-mannofuranoside ,  Methyl 2,3-O-(1-acetyl-2-methyl-1-azapropane-1,2-diyl)-5-oxo-2,5-dideoxy-α-D-lyxo-pentofuranoside ,  (5S)-5-(Benzyloxy)-3-O,4-O-isopropylidene-2,5-anhydro-D-arabinose ,  Methyl 2,3-O-(1-acetyl-2-methyl-1-azapropane-1,2-diyl)-2,5,6-trideoxy-(6-¹³C)α-D-lyxo-hexa-5-enofuranoside ,  Benzyl 2-O,3-O-isopropylidene-5,6-dideoxy-(6-¹³C)α-D-lyxo-hexa-5-enofuranoside ,  Methyl 2,3-O-(1-acetyl-2-methyl-1-azapropane-1,2-diyl)-5,6-anhydro-2-deoxy-(6-¹³C)α-D-mannofuranoside ,  Benzyl 2-O,3-O-isopropylidene-5,6-anhydro-(6-¹³C)α-D-mannofuranoside ,  Methyl 2,3-O-(1-acetyl-2-methyl-1-azapropane-1,2-diyl)-5,6-anhydro-2-deoxy-(6-¹³C)α-L-gulofuranoside ,  Benzyl 2-O,3-O-isopropylidene-5,6-anhydro-(6-¹³C)α-L-gulofuranoside ,  Methyl 2,3-O-(1-acetyl-2-methyl-1-azapropane-1,2-diyl)-2-deoxy-(6-¹³C)α-D-mannofuranoside ,  Benzyl 2-O,3-O-isopropylidene-(6-¹³C)α-D-mannofuranoside ,  2-(Acetylamino)-2-deoxy-(6-¹³C)D-mannopyranose ,  (6-¹³C)D-Mannopyranose ,  (4R)-2,4α-Dihydroxy-5β-(acetylamino)-6α-[(1R,2R)-1,2,3-trihydroxy(3-¹³C)propyl]tetrahydro-(3-¹³C)2H-pyran-2-carboxylic acid ,  (4R)-2,4α,5β-Trihydroxy-6α-[(1R,2S)-1,2,3-trihydroxy(3-¹³C)propyl]tetrahydro(3-¹³C)-2H-pyran-2-carboxylic acid ,  (4R)-2,4α-Dihydroxy-5β-(acetylamino)-6α-[(1R,2S)-1,2,3-trihydroxypropyl]tetrahydro(3-¹³C)-2H-pyran-2-carboxylic acid ,  (4R)-2,4α,5β-Trihydroxy-6α-[(1R,2S)-1,2,3-trihydroxypropyl]tetrahydro(3-¹³C)-2H-pyran-2-carboxylic acid ,  (4S)-2,4α-Dihydroxy-5β-(acetylamino)-6α-[(1R,2S)-1,2,3-trihydroxy(3-¹³C)propyl]tetrahydro-2H-pyran-2-carboxylic acid ,  (4S)-2,4α,5β-Trihydroxy-6α-[(1R,2S)-1,2,3-trihydroxy(3-¹³C)propyl]tetrahydro-2H-pyran-2-carboxylic acid ,  (3-¹³C)Pyruvic acid

Terms in the title (4)： 標識化 ,  KDN ,  化学 ,  酵素的合成