Proj
J-GLOBAL ID：200904073776799951
Research Project code：9800039140
Update date：Dec. 15, 2003
Development of the method for determining the structures of paramagnetic organometallic complexes with other nuclear NMR
常磁性有機金属錯体の他核NMR測定法の開発
Study period：1996 - 1996
Organization (1)：
Investigating Researcher (4)：
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Research overview：
We synthesyze three kinds of organometallic complexes which have dianagnetic metals and paramagnetic ligands, paramagnetic metals and diamagnetic ligands, or paramagnetic metals and paramagnetic ligands. Measurement of other nuclear NMR for these complexes and consideration for the effects of paramagnetism on metals and ligands are planned. Cr(3) or Ni(2) is used as paramagnetic metals. Co(3) or Rh(2) is taken as diamagnetic metals. We employ nitroxyl nitroxide radical as paramagnetic ligands and pyrazolato-3.5-dicarboxylato as diamagnetic ones.
Keywords (6)：
paramagnetism
, diamagnetism
, complex
, metal
, organometallic
, NMR
Ordinary Research
Research budget：
1996: \250,000
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