Research Project code：9800039140
Update date：Dec. 15, 2003
Development of the method for determining the structures of paramagnetic organometallic complexes with other nuclear NMR
1996 - 1996
Investigating Researcher (4)：
We synthesyze three kinds of organometallic complexes which have dianagnetic metals and paramagnetic ligands, paramagnetic metals and diamagnetic ligands, or paramagnetic metals and paramagnetic ligands. Measurement of other nuclear NMR for these complexes and consideration for the effects of paramagnetism on metals and ligands are planned. Cr(3) or Ni(2) is used as paramagnetic metals. Co(3) or Rh(2) is taken as diamagnetic metals. We employ nitroxyl nitroxide radical as paramagnetic ligands and pyrazolato-3.5-dicarboxylato as diamagnetic ones.
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