Chem
J-GLOBAL ID:200907018109766859   Nikkaji number:J2.334.712A

1-O-(1-Lithiopropadienyl)-2-deoxy-3-O,4-O,6-O-tris(tert-butyldimethylsilyl)-α-D-glucopyranose

1-O-(1-リチオプロパジエニル)-2-デオキシ-3-O,4-O,6-O-トリス(tert-ブチルジメチルシリル)-α-D-グルコピラノース
Substance type:
Substance type
Substance type classified into 3 categories.
Decided structure: Substances with a clear structure
Undicided Structure: Substances with unknown or undetermined structure
Mixtures: Mixtures, racemic compounds, or compounds with relative structural arrangements
Decided structure
Molecular formula: C27H55LiO5Si3
Molecular formula furigana: C27-H55-LI-O5-SI3
Molecular weight: 550.930
InChI: InChI=1S/C27H55O5Si3.Li/c1-17-18-28-23-19-21(31-34(13,14)26(5,6)7)24(32-35(15,16)27(8,9)10)22(30-23)20-29-33(11,12)25(2,3)4;/h21-24H,1,19-20H2,2-16H3;/t21-,22-,23+,24+;/m1./s1
InChI key: MZERJMNXZIMQHB-LAWPPSANSA-N
SMILES: [Li]C(=C=C)O[C@@H]1C[C@@H](O[Si](C)(C)C(C)(C)C)[C@H](O[Si](C)(C)C(C)(C)C)[C@@H](CO[Si](C)(C)C(C)(C)C)O1
Systematic name  (4):
  • 1-O-(1-リチオプロパジエニル)-2-デオキシ-3-O,4-O,6-O-トリス(tert-ブチルジメチルシリル)-α-D-グルコピラノース
  • 1-O-(1-リチオプロパジエニル)-3-O,4-O,6-O-トリス(tert-ブチルジメチルシリル)-2-デオキシ-α-D-arabino-ヘキソピラノース
  • {[(2R,3R,4R,6R)-3,4-ビス[(tert-ブチルジメチルシリル)オキシ]-6-[(1-リチオプロパ-1,2-ジエン-1-イル)オキシ]オキサン-2-イル]メトキシ}(tert-ブチル)ジメチルシラン
  • {[(2R,3R,4R,6R)-3,4-bis[(tert-butyldimethylsilyl)oxy]-6-[(1-lithiopropa-1,2-dien-1-yl)oxy]oxan-2-yl]methoxy}(tert-butyl)dimethylsilane
Other name (2):
  • 1-O-(1-Lithiopropadienyl)-2-deoxy-3-O,4-O,6-O-tris(tert-butyldimethylsilyl)-α-D-glucopyranose
  • 1-O-(1-Lithiopropadienyl)-3-O,4-O,6-O-tris(tert-butyldimethylsilyl)-2-deoxy-α-D-arabino-hexopyranose
Thsaurus map:

Return to Previous Page