Chem
J-GLOBAL ID:200907027399582046   Nikkaji number:J1.937.477G

4β-Methyl-4-(tert-butyldiphenylsilyloxymethyl)-5α-[(E)-1-methyl-1-propenyl]-4,5-dihydrofuran-2(3H)-one

(4R,5S)-5-[(2E)-ブタ-2-エン-2-イル]-4-{[(tert-ブチルジフェニルシリル)オキシ]メチル}-4-メチルオキソラン-2-オン
Substance type:
Substance type
Substance type classified into 3 categories.
Decided structure: Substances with a clear structure
Undicided Structure: Substances with unknown or undetermined structure
Mixtures: Mixtures, racemic compounds, or compounds with relative structural arrangements
Decided structure
Molecular formula: C26H34O3Si
Molecular formula furigana: C26-H34-O3-SI
Molecular weight: 422.640
InChI: InChI=1S/C26H34O3Si/c1-7-20(2)24-26(6,18-23(27)29-24)19-28-30(25(3,4)5,21-14-10-8-11-15-21)22-16-12-9-13-17-22/h7-17,24H,18-19H2,1-6H3/b20-7+/t24-,26+/m0/s1
InChI key: ONBVIYSMQULUHC-ZDODTOHDSA-N
SMILES: C/C=C(\C)/[C@@H]1OC(=O)C[C@]1(C)CO[Si](c1ccccc1)(c1ccccc1)C(C)(C)C
Systematic name  (4):
  • (4R)-4-メチル-4α-[(tert-ブチルジフェニルシロキシ)メチル]-5α-[(E)-1-メチル-1-プロペニル]-4,5-ジヒドロフラン-2(3H)-オン
  • 4β-メチル-4-(tert-ブチルジフェニルシリルオキシメチル)-5α-[(E)-1-メチル-1-プロペニル]-4,5-ジヒドロフラン-2(3H)-オン
  • (4R,5S)-5-[(2E)-ブタ-2-エン-2-イル]-4-{[(tert-ブチルジフェニルシリル)オキシ]メチル}-4-メチルオキソラン-2-オン
  • (4R,5S)-5-[(2E)-but-2-en-2-yl]-4-{[(tert-butyldiphenylsilyl)oxy]methyl}-4-methyloxolan-2-one
Other name (2):
  • (4R)-4-Methyl-4α-[(tert-butyldiphenylsiloxy)methyl]-5α-[(E)-1-methyl-1-propenyl]-4,5-dihydrofuran-2(3H)-one
  • 4β-Methyl-4-(tert-butyldiphenylsilyloxymethyl)-5α-[(E)-1-methyl-1-propenyl]-4,5-dihydrofuran-2(3H)-one
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