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J-GLOBAL ID：201002209373874638   Reference number：10A0196852

Regioselective Oxidation of Pyrrole Derivatives with DDQ and Its Synthetic Application

DDQによるピロール誘導体の位置選択的酸化とその合成への適用

Author (3)： IWAMOTO Ryoji (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  UKAJI Yutaka (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  INOMATA Katsuhiko (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 39  Issue： 3  Page： 176-177 (J-STAGE)  Publication year： 2010 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  regiospecific reaction ,  oxidation ,  chemical synthesis ,  nucleophilic reagent ,  Grignard reagent ,  fatty acid ,  regioselective reaction ,  *Pyrroles ,  drug
Semi thesaurus term： *Pyrroles

JST classification (1)： Pyrroles  (CF07076L)

Substance index (18)： DBU ,  DDQ ,  Acetic acid ,  2-(tert-Butoxycarbonyl)-4-methyl-1H-pyrrole-3-propanoic acid allyl ester ,  3-Ethyl-4-methyl-1H-pyrrole-2-carboxylic acid tert-butyl ester ,  2-(tert-Butoxycarbonyl)-4-formyl-1H-pyrrole-3-propanoic acid allyl ester ,  3-Ethyl-4-formyl-1H-pyrrole-2-carboxylic acid tert-butyl ester ,  3-Methyl-4-formyl-1H-pyrrole-2-carboxylic acid tert-butyl ester ,  3-Ethyl-4-acetyl-1H-pyrrole-2-carboxylic acid tert-butyl ester ,  2-(tert-Butoxycarbonyl)-4-(acetoxymethyl)-1H-pyrrole-3-propanoic acid allyl ester ,  3-Ethyl-4-(acetoxymethyl)-1H-pyrrole-2-carboxylic acid tert-butyl ester ,  3-Methyl-4-(1-acetoxyethyl)-1H-pyrrole-2-carboxylic acid tert-butyl ester ,  2-Tosyl-3-methyl-4-(1-acetoxyethyl)-1H-pyrrole ,  3-Ethyl-4-(1-acetoxyethyl)-1H-pyrrole-2-carboxylic acid tert-butyl ester ,  2-(tert-Butoxycarbonyl)-4-(tosylmethyl)-1H-pyrrole-3-propanoic acid allyl ester ,  2-(tert-Butoxycarbonyl)-4-(2-nitroethyl)-1H-pyrrole-3-propanoic acid allyl ester ,  2-(tert-Butoxycarbonyl)-4-pentyl-1H-pyrrole-3-propanoic acid allyl ester ,  2-(tert-Butoxycarbonyl)-4-[(E)-2-phenylethenyl]-1H-pyrrole-3-propanoic acid allyl ester

Reference (22)：

• 1) K. Inomata, Bull. Chem. Soc. Jpn. 2008, 81, 25, and references cited therein.
• 2) M. A. S. Hammam, Y. Murata, H. Kinoshita, K. Inomata, Chem. Lett. 2004, 33, 1258;
•  H. Kinoshita, M. A. S. Hammam, K. Inomata, Chem. Lett. 2005, 34, 800;
•  K. Inomata, M. A. S. Hammam, H. Kinoshita, Y. Murata, H. Khawn, S. Noack, N. Michael, T. Lamparter, J. Biol. Chem. 2005, 280, 24491;
•  M. A. S. Hammam, H. Nakamura, Y. Hirata, H. Khawn, Y. Murata, H. Kinoshita, K. Inomata, Bull. Chem. Soc. Jpn. 2006, 79, 1561;

Terms in the title (3)： DDQ ,  ピロール誘導体 ,  選択的酸化