Art

J-GLOBAL ID：201002214167370228   Reference number：10A1138495

A Simple and Efficient Synthesis of Functionalized Cyclic Carbonate Monomers Using a Versatile Pentafluorophenyl Ester Intermediate

多目的ペンタフルオロフェニルエステル中間体を利用しての官能基化環状炭酸エステルモノマの簡単かつ効率的合成法

Author (7)： SANDERS Daniel P. (IBM Almaden Res. Center, California, USA) ,  FUKUSHIMA Kazuki (IBM Almaden Res. Center, California, USA) ,  COADY Daniel J. (IBM Almaden Res. Center, California, USA) ,  NELSON Alshakim (IBM Almaden Res. Center, California, USA) ,  FUJIWARA Masaki (Central Glass International, Inc., California, USA) ,  YASUMOTO Manabu (Central Glass International, Inc., California, USA) ,  HEDRICK James L. (IBM Almaden Res. Center, California, USA)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 132  Issue： 42  Page： 14724-14726  Publication year： Oct. 27, 2010 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  *inorganic acid ester ,  organofluorine compound ,  synthetic intermediate ,  monomer ,  functionalization ,  cesium fluoride ,  biocompatibility ,  polymer ,  *polycarbonate ,  carbonic ester
Semi thesaurus term： biodegradable

JST classification (2)： Inorganic acid esters of aromatic monocyclic alcohols,phenols and thiols  (CF05120F) ,  Other polymeric materials  (YH07150C)

Substance index (16)： 2,2-Bis(hydroxymethyl)propionic acid ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid ethyl ester ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid 2,2,2-trifluoroethyl ester ,  5-(Benzyloxycarbonyl)-5-methyl-1,3-dioxane-2-one ,  5-(Allyloxycarbonyl)-5-methyl-1,3-dioxane-2-one ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid propargyl ester ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid 3-chloropropyl ester ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid 3-bromopropyl ester ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid 2-(2-methoxyethoxy)ethyl ester ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid 2-[(tetrahydro-2H-pyran-2-yl)oxy]ethyl ester ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid 2-(Boc-amino)ethyl ester ,  2,2-[Carbonylbis(oxymethylene)]propionic acid 2-(2-pyridyldithio)ethyl ester ,  2-Oxo-5-methyl-1,3-dioxane-5-carboxylic acid 2-[(2,4-dinitrophenyl)thio]ethyl ester ,  N-Benzyl-2-oxo-5-methyl-1,3-dioxane-5-carboxamide ,  N-Isopropyl-2-oxo-5-methyl-1,3-dioxane-5-carboxamide ,  N,N,5-Trimethyl-2-oxo-1,3-dioxane-5-carboxamide

Terms in the title (5)： 中間体 ,  官能基化 ,  環状炭酸エステル ,  モノマ ,  合成法