Synthesis of New Enantiomerically Pure Organoiodine Catalysts and Their Application in the α-Functionalization of Ketones

FAROOQ Umar; FAROOQ Umar; SCHAEFER Sascha; SHAH Azhar-ul-Haq Ali; SHAH Azhar-ul-Haq Ali; FREUDENDAHL Diana Maria; WIRTH Thomas

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J-GLOBAL ID：201002217766361260 Reference number：10A0354602

Synthesis of New Enantiomerically Pure Organoiodine Catalysts and Their Application in the α-Functionalization of Ketones

新規エナンチオマ純粋有機ヨウ素触媒及びケトン類のα-官能化におけるそれらの適用

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Author (7)：

FAROOQ Umar

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(Cardiff Univ., Cardiff, GBR)

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FAROOQ Umar

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(COMSATS Inst. of Information Technol., Abbottabad, PAK)

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SCHAEFER Sascha

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(Cardiff Univ., Cardiff, GBR)

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SHAH Azhar-ul-Haq Ali

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(Cardiff Univ., Cardiff, GBR)

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SHAH Azhar-ul-Haq Ali

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(Kohat Univ. Sci. and Technol., Kohat, PAK)

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FREUDENDAHL Diana Maria

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(Cardiff Univ., Cardiff, GBR)

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WIRTH Thomas

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(Cardiff Univ., Cardiff, GBR)

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Material：

Synthesis (Journal of Synthetic Organic Chemistry)

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Issue： 6 Page： 1023-1029 Publication year： Mar. 16, 2010
JST Material Number： D0738A ISSN： 0039-7881 CODEN： SYNTBF Document type： Article
Article type：原著論文 Country of issue： Germany, Federal Republic of (DEU) Language： ENGLISH (EN)

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asymmetric synthesis

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*aromatic iodine compound

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ketone

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regiospecific reaction

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sulfonate

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functionalization

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lactonization

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*catalytic activity

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*catalyst

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Esterification

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aromatic carboxylic acid

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*carboxylate (ester)

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aromatic ketone

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*organic catalyst

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JST classification (1)：

JST classification
Category name(code) classified by JST.

Aromatic monocyclic carboxylic esters,carboxylic anhydrides,acid halides

(CF05190E)

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Substance index (14)：

Substance index
Chemical Substance indexed to the Article.

Propiophenone

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5-Oxo-5-phenylpentanoic acid

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(R)-α-(Tosyloxy)propiophenone

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(2R,3R)-2-Hydroxy-3-(2-iodophenylacetoxy)butanedioic acid diethyl ester

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(2R,3R)-2-Hydroxy-3-(2-iodophenylacetoxy)butanedioic acid dimethyl ester

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2-Iodobenzeneacetic acid (S)-α-methylbenzyl ester

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2-Iodobenzeneacetic acid

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2-Iodobenzoic acid (S)-α-methylbenzyl ester

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2-Iodobenzoic acid (S)-α-methyl-2-bromobenzyl ester

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3-Iodobenzoic acid (S)-α-methyl-2-bromobenzyl ester

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2-Iodobenzeneacetic acid (S)-α-methyl-2-bromobenzyl ester

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2-Iodobenzoic acid (1R)-1β-bromoindan-2α-yl ester

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2-Iodobenzeneacetic acid (8α,9S)-6′-methoxy-10,11-dihydrocinchonan-9-yl ester

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5-Benzoyltetrahydrofuran-2-one

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Terms in the title (4)：

Terms in the title
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エナンチオマ

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ヨウ素触媒

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ケトン類

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官能化

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