Art

J-GLOBAL ID：201002229885242871   Reference number：10A0948719

Asymmetric Synthesis of γ-Hydroxy α-Enones by 1,8-Diazabicyclo[5.4.0]undec-7-ene-Catalyzed Stereoselective Rearrangement of Chiral α-Sulfinyl Enones

キラルなα-スルフィニルエノンの1,8-ジアザビシクロ[5.4.0]ウンデカ-7-エン-接触立体選択的転位反応によるγ-ヒドロキシ-α-エノンの不斉合成

Author (6)： MIURA Motofumi (Nihon Univ., Chiba, JPN) ,  TORIYAMA Masaharu (Nihon Univ., Chiba, JPN) ,  KAWAKUBO Takashi (Jikei Univ., Tokyo, JPN) ,  YASUKAWA Ken (Nihon Univ., Chiba, JPN) ,  TAKIDO Toshio (Nihon Univ., Chiyodaku, JPN) ,  MOTOHASHI Shigeyasu (Nihon Univ., Chiba, JPN)
Material： Organic Letters  (Org Lett)
Volume： 12  Issue： 17  Page： 3882-3885  Publication year： Sep. 03, 2010 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  rearrangement reaction ,  catalytic reaction ,  *enone ,  sulfoxide ,  amine ,  *hydroxy ketone ,  unsaturated alcohol ,  nitrogen heterocyclic compound ,  organic catalysis

JST classification (1)： Aromatic monocyclic ketones  (CF05170I)

Substance index (14)： DBU ,  (E)-4-(4-Methylphenylsulfinyl)-1,7-diphenyl-4-heptene-3-one ,  Alpinoid C ,  (R,E)-4-Hydroxy-1,5-diphenyl-2-pentene-1-one ,  (R,E)-2-Methyl-7-hydroxy-8-phenyl-5-octene-4-one ,  (R,E)-7-Hydroxy-8-phenyl-5-octene-4-one ,  (R,E)-2-Methyl-6-hydroxy-7-phenyl-4-heptene-3-one ,  (R,E)-4-Hydroxy-1-phenyl-2-octene-1-one ,  (R,E)-6-Hydroxy-1-phenyl-4-decene-3-one ,  (R,E)-5-Hydroxy-1,1-diphenyl-3-nonene-2-one ,  (R,E)-5-Methyl-4-hydroxy-1-phenyl-2-hexene-1-one ,  (R,E)-7-Methyl-6-hydroxy-1-phenyl-4-octene-3-one ,  (R,E)-1-Phenyl-4-cyclopentyl-4-hydroxy-2-butene-1-one ,  (R,E)-1-Phenyl-6-cyclopentyl-6-hydroxy-4-hexene-1-one

Terms in the title (5)： キラル ,  立体 ,  転位反応 ,  エノン ,  不斉合成