Art

J-GLOBAL ID：201002264456421555   Reference number：10A0122571

The reaction of 1-silylcyclopropyl anions with dichloromethyl methyl ether: the efficient synthesis of cyclopropyl silyl ketones via cyclopropylidene derivatives

1-シリルシクロプロピルアニオン類とジクロロメチルメチルエーテルとの反応: シクロプロピリデン誘導体を経るシクロプロピルシリルケトン類の効率的合成

Author (5)： NISHIZAWA Toshiaki (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ., Kakuma-machi, Kanazawa ...) ,  NAKAE Kenta (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ., Kakuma-machi, Kanazawa ...) ,  HONDA Mitsunori (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ., Kakuma-machi, Kanazawa ...) ,  KUNIMOTO Ko-ki (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ., Kakuma-machi, Kanazawa ...) ,  SEGI Masahito (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ., Kakuma-machi, Kanazawa ...)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 51  Issue： 9  Page： 1294-1297  Publication year： Mar. 03, 2010 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *organosilicon compound ,  *alicyclic compound ,  *ketone ,  chemical synthesis ,  olefin compound ,  Hydrolysis ,  carbanion ,  ether ,  reaction mechanism ,  carbene ,  rearrangement reaction ,  Cyclopropanes

JST classification (3)： Organosilicon compounds  (CF08030C) ,  Aliphatic ethers  (CF03100V) ,  Cyclopropanes  (CF04020P)

Substance index (13)： Methyl (dichloromethyl) ether ,  1β-(Trimethylsilyl)-1-bromo-2β-phenylcyclopropane ,  [(1α)-2β-Phenylcyclopropyl](trimethylsilyl) ketone ,  (1R)-1α-Phenyl-2-[methoxy(trimethylsilyl)methylene]cyclopropane ,  (1R)-1α-Phenyl-2-[methoxy(phenyldimethylsilyl)methylene]cyclopropane ,  (1R)-1α-Phenyl-2-[methoxy(triethylsilyl)methylene]cyclopropane ,  1,1-Dimethyl-2-[methoxy(trimethylsilyl)methylene]cyclopropane ,  (1R)-1α,2β-Dimethyl-3-[methoxy(trimethylsilyl)methylene]cyclopropane ,  (1R)-1α,2β-Dimethyl-3-[methoxy(phenyldimethylsilyl)methylene]cyclopropane ,  1-[Methoxy(trimethylsilyl)methylene]-2β,3β-dimethylcyclopropane ,  7-[Methoxy(trimethylsilyl)methylene]bicyclo[4.1.0]heptane ,  (1S)-1α-Phenyl-2-(trimethylsilylcarbonyl)cyclopropane ,  (1R)-1α-Phenyl-2-chloro-2-(trimethylsilylcarbonyl)cyclopropane

Terms in the title (2)： ジクロロメチルメチルエーテル ,  誘導体