Art

J-GLOBAL ID：201002269126939444   Reference number：10A0070852

Chiral Bronsted Acid-Catalyzed Enantioselective Multicomponent Mannich Reaction: Synthesis of anti-1,3-Diamines Using Enecarbamates as Nucleophiles

キラルBroensted酸接触エナンチオ選択的多成分Mannich反応 求核試薬としてエンカルバミド酸エステルを用いたanti-ジアミンの合成

Author (4)： DAGOUSSET Guillaume (Inst. Chimie des Substances Naturelles, CNRS, Gif-sur-Yvette, FRA) ,  DROUET Fleur (Inst. Chimie des Substances Naturelles, CNRS, Gif-sur-Yvette, FRA) ,  MASSON Geraldine (Inst. Chimie des Substances Naturelles, CNRS, Gif-sur-Yvette, FRA) ,  ZHU Jieping (Inst. Chimie des Substances Naturelles, CNRS, Gif-sur-Yvette, FRA)
Material： Organic Letters  (Org Lett)
Volume： 11  Issue： 23  Page： 5546-5549  Publication year： Dec. 03, 2009 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  catalytic reaction ,  Broensted acid ,  phosphoric acid ,  inorganic acid ester ,  organophosphorus compound ,  aldehyde ,  aromatic amine ,  carbamate ,  vinyl compound ,  *Mannich reaction ,  *reduction(reaction) ,  one-pot synthesis ,  *diamine ,  enantiomer ,  oxygen heterocyclic compound
Semi thesaurus term： Aniline Compounds ,  Phosphoric Acid Esters ,  three-component reaction

JST classification (3)： Aromatic monocyclic amine,imine,quaternary ammonium,immonium compounds  (CF05050D) ,  Aliphatic ureas,carbamic acids,guanidines  (CF03240W) ,  Catalytic reactions in general  (CB06080F)

Substance index (18)： Furfural ,  4-Nitroaniline ,  4-Bromobenzaldehyde ,  1-Propenylcarbamic acid benzyl ester ,  N-[(2S,3R)-2,3-Bis[(4-nitrophenyl)amino]pentyl]carbamic acid benzyl ester ,  N-[(2S,3R)-2-Methyl-3-[(4-nitrophenyl)amino]-5-phenyl-4-pentenyl]carbamic acid benzyl ester ,  N-[(2S,3S)-2-Methyl-3-[(4-nitrophenyl)amino]-3-(1,1′-biphenyl-4-yl)propyl]carbamic acid benzyl ester ,  N-[(2S,3S)-2-Methyl-3-[(4-nitrophenyl)amino]-3-(2-furanyl)propyl]carbamic acid benzyl ester ,  N-[(2S,3S)-2-Methyl-3-[(4-nitrophenyl)amino]-3-(2-bromophenyl)propyl]carbamic acid benzyl ester ,  N-[(2S,3S)-2-Methyl-3-[(4-nitrophenyl)amino]-3-(4-methoxyphenyl)propyl]carbamic acid benzyl ester ,  N-[(2S,3S)-2-Methyl-3-[(4-nitrophenyl)amino]-3-phenylpropyl]carbamic acid benzyl ester ,  N-[(R)-3-[(4-Nitrophenyl)amino]pentyl]carbamic acid benzyl ester ,  N-[(S)-3-[(4-Nitrophenyl)amino]-3-(2-furanyl)propyl]carbamic acid benzyl ester ,  N-[(S)-3-[(4-Nitrophenyl)amino]-3-(4-bromophenyl)propyl]carbamic acid benzyl ester ,  N-[(S)-3-[(4-Nitrophenyl)amino]-3-(4-methoxyphenyl)propyl]carbamic acid benzyl ester ,  N-[(S)-3-[(4-Nitrophenyl)amino]-4-methylpentyl]carbamic acid benzyl ester ,  N-[(S)-3-[(4-Nitrophenyl)amino]-5-phenyl-4-pentenyl]carbamic acid benzyl ester ,  N-Ethenylcarbamic acid benzyl ester

Terms in the title (6)： キラル ,  Broensted酸 ,  Mannich反応 ,  求核試薬 ,  カルバミド酸エステル ,  ジアミン