Art

J-GLOBAL ID：201002279343462406   Reference number：10A0323196

Addition of alkyl radicals, generated from carboxylic acids via photochemical decarboxylation, to glyoxylic oxime ether: a mild and efficient route to α-substituted α-aminoesters

光化学的脱炭酸反応を経てカルボン酸から発生したアルキルラジカルのグリオキシル酸オキシムエーテルへの付加: α-置換α-アミノエステルへの穏やかでかつ効率的なルート

Author (10)： YOSHIMI Yasuharu (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Univ. of Fukui, 3-9-1 Bunkyo, Fukui ...) ,  KOBAYASHI Kosuke (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Univ. of Fukui, 3-9-1 Bunkyo, Fukui ...) ,  KAMAKURA Hayato (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Univ. of Fukui, 3-9-1 Bunkyo, Fukui ...) ,  NISHIKAWA Keisuke (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Univ. of Fukui, 3-9-1 Bunkyo, Fukui ...) ,  HAGA Yoshiki (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Univ. of Fukui, 3-9-1 Bunkyo, Fukui ...) ,  MAEDA Kousuke (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Univ. of Fukui, 3-9-1 Bunkyo, Fukui ...) ,  MORITA Toshio (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Univ. of Fukui, 3-9-1 Bunkyo, Fukui ...) ,  ITOU Tatsuya (Dep. of Applied Chemistry, Coll. of Life Sciences, Ritsumeikan Univ., 1-1-1 Noji-Higashi, Kusatsu 525-8577, JPN) ,  OKADA Yutaka (Dep. of Applied Chemistry, Coll. of Life Sciences, Ritsumeikan Univ., 1-1-1 Noji-Higashi, Kusatsu 525-8577, JPN) ,  HATANAKA Minoru (Dep. of Medicinal and Organic Chemistry, School of Pharmacy, Iwate Medical Univ., Yahaba, Iwate 028-3694, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 51  Issue： 17  Page： 2332-2334  Publication year： Apr. 28, 2010 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： aliphatic aldehyde ,  aliphatic carboxylic acid ,  *oxime ether ,  decarboxylation reaction ,  photochemical reaction ,  *alkyl radical ,  addition reaction ,  *amino acid ,  *carboxylate(ester) ,  chemical synthesis ,  carboxylic acid ,  alicyclic compound ,  fatty acid ,  aromatic nitrile

JST classification (2)： Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P) ,  Photochemical reaction,radical reaction  (CF02090A)

Substance index (11)： Glyoxylic acid ,  Cyclohexanecarboxylic acid ,  N-Boc-L-Valine ,  Boc-Phenylalanine ,  Pivalic acid ,  Terephthalonitrile ,  Methyl (benzyloxyimino)acetate ,  α-(Benzyloxyimino)cyclohexaneacetic acid methyl ester ,  2-(Benzyloxyimino)-3,3-dimethylbutanoic acid methyl ester ,  (3S)-2-(Benzyloxyimino)-3-(tert-butoxycarbonylamino)-4-methylpentanoic acid methyl ester ,  (3S)-2-(Benzyloxyimino)-3-(tert-butoxycarbonylamino)-4-phenylbutanoic acid methyl ester

Terms in the title (8)： 光化学 ,  脱炭酸反応 ,  カルボン酸 ,  アルキルラジカル ,  グリオキシル酸オキシム ,  エーテル ,  置換 ,  エステル