Art

J-GLOBAL ID：201102202070904383   Reference number：11A0294862

Rhodium-Catalyzed Asymmetric 1,4-Addition of Sodium Tetraarylborates to β,β-Disubstituted α,β-Unsaturated Esters

ナトリウムテトラアリールボラートのβ,β-二置換α,β-不飽和エステルへのロジウム接触不斉1,4-付加

Author (2)： SHINTANI Ryo (Kyoto Univ., Kyoto, JPN) ,  HAYASHI Tamio (Kyoto Univ., Kyoto, JPN)
Material： Organic Letters  (Org Lett)
Volume： 13  Issue： 2  Page： 350-352  Publication year： Jan. 21, 2011 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *organoboron compound ,  *unsaturated carboxylic acid ,  carboxylate (ester) ,  olefin compound ,  asymmetric reaction ,  *addition reaction ,  *rhodium catalyst ,  reaction mechanism

JST classification (3)： Organoboron compounds  (CF08020R) ,  Aromatic monocyclic carboxylic esters,carboxylic anhydrides,acid halides  (CF05190E) ,  Nobel metal catalysts  (CB06122I)

Substance index (16)： Tetraphenylboron sodium ,  (E)-3-Methyl-5-phenyl-2-pentenoic acid methyl ester ,  (E)-3-Methyl-5-phenyl-2-pentenoic acid 2,6-dimethylphenyl ester ,  (S)-3-Methyl-3,5-diphenylpentanoic acid 2,6-dimethylphenyl ester ,  (R)-3-Methyl-3,5-diphenylpentanoic acid 2,6-dimethylphenyl ester ,  (S)-3-Ethyl-3,5-diphenylpentanoic acid 2,6-dimethylphenyl ester ,  (R)-3-Ethyl-3,5-diphenylpentanoic acid 2,6-dimethylphenyl ester ,  (S)-3,7-Dimethyl-3-phenyl-6-octenoic acid 2,6-dimethylphenyl ester ,  (S)-3-(4-Chlorophenyl)-3-phenylbutanoic acid 2,6-dimethylphenyl ester ,  (S)-3-Methyl-3-(4-methoxyphenyl)-5-phenylpentanoic acid 2,6-dimethylphenyl ester ,  (S)-3-Methyl-3-(4-methylphenyl)-5-phenylpentanoic acid 2,6-dimethylphenyl ester ,  (S)-3-Methyl-3-(4-chlorophenyl)-5-phenylpentanoic acid 2,6-dimethylphenyl ester ,  (S)-3-Methyl-3-(3-methylphenyl)-5-phenylpentanoic acid 2,6-dimethylphenyl ester ,  Dehydromevalonolactone ,  4β-Methyl-4-phenyltetrahydro-2H-pyran-2-one ,  3β-Methyl-3-phenethylindan-1-one

Terms in the title (3)： 置換 ,  不飽和エステル ,  ロジウム