Art
J-GLOBAL ID：201102202240253846   Reference number：11A1038964

Stereochemically Controlled Asymmetric 1,2-Reduction of Enones Mediated by a Chiral Sulfoxide Moiety and a Lanthanum(III) Ion

キラルなスルホキシド部とランタン(III)イオンによリ媒介されるエノンの立体化学的に制御された不斉1,2-還元
Author (9)：
MOTOHASHI Shigeyasu

About MOTOHASHI Shigeyasu

(Nihon Univ., Chiba, JPN)

About Nihon Univ., Chiba, JPN

, 
NAGASE Kouichi

About NAGASE Kouichi

(Nihon Univ., Chiba, JPN)

About Nihon Univ., Chiba, JPN

, 
NAKAKITA Toshinori

About NAKAKITA Toshinori

(Nihon Univ., Chiba, JPN)

About Nihon Univ., Chiba, JPN

, 
MATSUO Takeshi

About MATSUO Takeshi

(Nihon Univ., Chiba, JPN)

About Nihon Univ., Chiba, JPN

, 
YOSHIDA Yoshikazu

About YOSHIDA Yoshikazu

(Nihon Univ. Itabashi Hospital, Tokyo, JPN)

About Nihon Univ. Itabashi Hospital, Tokyo, JPN

, 
KAWAKUBO Takashi

About KAWAKUBO Takashi

(Jikei Univ., Tokyo, JPN)

About Jikei Univ., Tokyo, JPN

, 
MIURA Motofumi

About MIURA Motofumi

(Nihon Univ., Chiba, JPN)

About Nihon Univ., Chiba, JPN

, 
TORIYAMA Masaharu

About TORIYAMA Masaharu

(Nihon Univ., Chiba, JPN)

About Nihon Univ., Chiba, JPN

, 
BARYBIN Mikhail V.

About BARYBIN Mikhail V.

(Univ. Kansas, Kansas, USA)

About Univ. Kansas, Kansas, USA


Material：
Journal of Organic Chemistry  (J Org Chem)

About Journal of Organic Chemistry


Volume： 76  Issue： 10  Page： 3922-3936  Publication year： May. 20, 2011 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)
Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
*sulfoxide

About sulfoxide

, 
*enone

About enone

, 
*asymmetric reduction

About asymmetric reduction

, 
unsaturated alcohol

About unsaturated alcohol

, 
lanthanum chloride

About lanthanum chloride

, 
chelating reagent

About chelating reagent

, 
stereospecific reaction

About stereospecific reaction

, 
sodium hydridoborate

About sodium hydridoborate

, 
reaction mechanism

About reaction mechanism


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
*allyl alcohols

About allyl alcohols

, 
chiral auxiliary

About chiral auxiliary

, 
*lanthanum-ion

About lanthanum-ion


JST classification (2)：
JST classification
Category name(code) classified by JST.
Aromatic monocyclic sulfonic acids,sulfinic acids,sulfenic acids 
(CF05140B)

About Aromatic monocyclic sulfonic acids,sulfinic acids,sulfenic acids

,  Oxidation,reduction 
(CF02060T)

About Oxidation,reduction

Substance index (4)：
Substance index
Chemical Substance indexed to the Article.
(2R,3Z)-3-Methyl-4-[(4-methylphenyl)sulfinyl]-3-pentene-2-ol

About (2R,3Z)-3-Methyl-4-[(4-methylphenyl)sulfinyl]-3-pentene-2-ol

, 
(2S,3Z)-3-Methyl-4-[(4-methylphenyl)sulfinyl]-3-pentene-2-ol

About (2S,3Z)-3-Methyl-4-[(4-methylphenyl)sulfinyl]-3-pentene-2-ol

, 
(3Z)-3-Methyl-4-[(4-methylphenyl)sulfinyl]-3-pentene-2-one

About (3Z)-3-Methyl-4-[(4-methylphenyl)sulfinyl]-3-pentene-2-one

, 
Diisobutyl aluminum hydride

About Diisobutyl aluminum hydride

Terms in the title (7)：
Terms in the title
Keywords automatically extracted from the title.
キラル

About キラル

, 
スルホキシド

About スルホキシド

, 
ランタン

About ランタン

, 
イオン

About イオン

, 
エノン

About エノン

, 
立体化学

About 立体化学

, 
還元

About 還元


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