Art
J-GLOBAL ID：201102222793570670   Reference number：11A1938449

Total synthesis of (R)-(-)-actisonitrile via O-alkylation of optically active 4-hydroxymethyloxazolidin-2-one derivative

光学活性4-ヒドロキシメチルオキサゾリジン-2-オン誘導体のO-アルキル化を経由する(R)-(-)-アクトイソニトリルの全合成
Author (4)：
SUGIYAMA Shigeo

About SUGIYAMA Shigeo

(Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN)

About Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN

, 
ISHIDA Akihiro

About ISHIDA Akihiro

(Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN)

About Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN

, 
TSUCHIDA Moeko

About TSUCHIDA Moeko

(Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN)

About Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN

, 
ISHII Keitaro

About ISHII Keitaro

(Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN)

About Dep. of Life and Pharmaceutical Sciences, Meiji Pharmaceutical Univ., 2-522-1 Noshio, Kiyose, Tokyo 204-8588, JPN


Material：
Tetrahedron: Asymmetry  (Tetrahedron Asym)

About Tetrahedron: Asymmetry


Volume： 22  Issue： 20-22  Page： 1918-1923  Publication year： Nov. 30, 2011 
JST Material Number： T0907A  ISSN： 0957-4166  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)
Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
total synthesis

About total synthesis

, 
*aliphatic isocyanide

About aliphatic isocyanide

, 
*ether

About ether

, 
*alkylation

About alkylation

, 
oxygen heterocyclic compound

About oxygen heterocyclic compound

, 
nitrogen heterocyclic compound

About nitrogen heterocyclic compound

, 
ketone

About ketone

, 
carbamate

About carbamate

, 
etherification

About etherification

, 
aliphatic iodine compound

About aliphatic iodine compound


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
oxazolidine derivative

About oxazolidine derivative


JST classification (2)：
JST classification
Category name(code) classified by JST.
Oxazoles,isoxazoles 
(CF07080Y)

About Oxazoles,isoxazoles

,  Aliphatic nitriles,isocyanides 
(CF03230L)

About Aliphatic nitriles,isocyanides

Substance index (10)：
Substance index
Chemical Substance indexed to the Article.
3-[(R)-α-Methylbenzyl]-4α-(hydroxymethyl)oxazolidine-2-one

About 3-[(R)-α-Methylbenzyl]-4α-(hydroxymethyl)oxazolidine-2-one

, 
(4R)-3-[(R)-α-Methylbenzyl]-4α-(hexadecyloxymethyl)oxazolidine-2-one

About (4R)-3-[(R)-α-Methylbenzyl]-4α-(hexadecyloxymethyl)oxazolidine-2-one

, 
3-[(S)-α-Methylbenzyl]-4α-(hydroxymethyl)-2-oxazolidinone

About 3-[(S)-α-Methylbenzyl]-4α-(hydroxymethyl)-2-oxazolidinone

, 
(4R)-3-[(S)-α-Methylbenzyl]-4α-(hexadecyloxymethyl)oxazolidine-2-one

About (4R)-3-[(S)-α-Methylbenzyl]-4α-(hexadecyloxymethyl)oxazolidine-2-one

, 
(4R)-4α-(Hexadecyloxymethyl)oxazolidine-2-one

About (4R)-4α-(Hexadecyloxymethyl)oxazolidine-2-one

, 
(2S)-2-Amino-4-oxaicosane-1-ol

About (2S)-2-Amino-4-oxaicosane-1-ol

, 
(-)-Actisonitrile

About (-)-Actisonitrile

, 
1-Iodohexadecane

About 1-Iodohexadecane

, 
(S)-2-(Formylamino)-3-(hexadecyloxy)-1-propanol

About (S)-2-(Formylamino)-3-(hexadecyloxy)-1-propanol

, 
Acetic acid (R)-2-(formylamino)-3-(hexadecyloxy)propyl ester

About Acetic acid (R)-2-(formylamino)-3-(hexadecyloxy)propyl ester

Terms in the title (6)：
Terms in the title
Keywords automatically extracted from the title.
光学活性

About 光学活性

, 
ヒドロキシメチル

About ヒドロキシメチル

, 
オキサゾリジン-2-オン

About オキサゾリジン-2-オン

, 
誘導体

About 誘導体

, 
アルキル化

About アルキル化

, 
全合成

About 全合成


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