Art

J-GLOBAL ID：201102227923144670   Reference number：11A0787695

Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes

多用途γ-四級アシルシクロペンテン類の実用的,拡張性,触媒的不斉合成の環収縮戦略

Author (6)： HONG Allen Y. (California Inst. of Technol., CA, USA) ,  KROUT Michael R. (California Inst. of Technol., CA, USA) ,  JENSEN Thomas (California Inst. of Technol., CA, USA) ,  BENNETT Nathan B. (California Inst. of Technol., CA, USA) ,  HARNED Andrew M. (California Inst. of Technol., CA, USA) ,  STOLTZ Brian M. (California Inst. of Technol., CA, USA)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 50  Issue： 12  Page： 2756-2760  Publication year： 2011 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *cycloalkene ,  alicyclic ketone ,  enone ,  *asymmetric synthesis ,  catalytic reaction ,  palladium catalyst ,  *ring contraction reaction ,  functionalization ,  substituent effect ,  enantiomer ,  stereospecific reaction ,  Alkylation ,  hydroxy ketone ,  purity ,  nucleophilic addition reaction ,  cyclopentenes
Semi thesaurus term： cyclopentene derivatives ,  optical purity

JST classification (1)： Cyclopentanes  (CF04040L)

Substance index (15)： (3S)-1-Acetyl-1′,3′,3a′,6′,7′,7a′-hexahydrospiro[cyclopentene-3,2′-[2H]indene] ,  1-(2-Butyl-3-methyl-3α-allyl-1-cyclopentenyl)ethanone ,  3β-Methyl-3-allyl-1-acetyl-1-cyclopentene ,  3β-Propargyl-3-allyl-1-acetyl-1-cyclopentene ,  1-[(E)-2-(3-Methyl-3α-allyl-1-cyclopentenyl)ethylidene]semicarbazide ,  3β-(2-Chloroallyl)-3-allyl-1-acetyl-1-cyclopentene ,  1-[3β-(tert-Butyldiphenylsiloxymethyl)-3-allyl-1-cyclopentenyl]ethanone ,  3β-[(E)-2,4-Pentadienyl]-3-allyl-1-acetyl-1-cyclopentene ,  1-[3-Methyl-3α-[3-(2-hydroxyphenyl)propyl]-1-cyclopentenyl]ethanone ,  1-Methyl-2-oxo-4-isobutoxy-3-cycloheptene-1-carboxylic acid allyl ester ,  2-(3-Methyl-3α-allyl-1-cyclopentenyl)-2-propanol ,  2-Methyl-2α-allyl-5-acetyl-6-oxabicyclo[3.1.0]hexane ,  3-Hydroxy-4α-allyl-4-methylcycloheptanone ,  7β-Allyl-7-(1-tosyl-1H-indole-3-ylmethyl)-3-isobutoxy-2-cycloheptene-1-one ,  3-Isobutoxy-7-allyl-7α-methyl-2-cycloheptene-1-one

Terms in the title (5)： 用途 ,  拡張性 ,  触媒的不斉合成 ,  収縮 ,  戦略