Art

J-GLOBAL ID：201102240778791715   Reference number：11A1474483

Solvent-induced anomeric diastereoselectivity switching using a single glycosyl donor

単一のグリコシルドナーを用いる溶媒誘起アノマー性ジアステレオ選択性切り替え

Author (2)： FUJIWARA Ryuta (Dep. of Biological Sci. & Technol., Tokyo Univ. of Sci., 2641 Yamazaki, Noda, Chiba 278-8510, JPN) ,  HORITO Shigeomi (Dep. of Biological Sci. & Technol., Tokyo Univ. of Sci., 2641 Yamazaki, Noda, Chiba 278-8510, JPN)
Material： Carbohydrate Research  (Carbohydr Res)
Volume： 346  Issue： 14  Page： 2098-2103  Publication year： Oct. 18, 2011 
JST Material Number： B0929A  ISSN： 0008-6215  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *glycosylation ,  stereoselectivity ,  diastereomer ,  *aldose ,  ketose ,  steric conformation ,  functional group protection ,  thiosugar ,  pyranoside ,  spin-lattice relaxation ,  relaxation time ,  molecular motion ,  alcohol ,  *solvent effect ,  aliphatic alcohol

JST classification (1)： Monosaccharides  (CF10052H)

Substance index (16)： 1-Decanol ,  2-O,3-O,4-O-Tribenzyl-1-ethylthio-1-deoxy-β-L-fucopyranose ,  2-O,3-O-Dibenzyl-4-O-benzoyl-1-ethylthio-1-deoxy-β-L-fucopyranose ,  2-O-Benzyl-3-O,4-O-dibenzoyl-1-ethylthio-1-deoxy-β-L-fucopyranose ,  8-(Ethoxycarbonyl)octyl 2-O,3-O-dibenzyl-4-O,6-O-dibenzoyl-α-D-galactopyranoside ,  8-(Ethoxycarbonyl)octyl 2-O,3-O-dibenzyl-4-O,6-O-dibenzoyl-β-D-galactopyranoside ,  8-(Ethoxycarbonyl)octyl 2-O,3-O-dibenzyl-4-O-benzoyl-α-L-fucopyranoside ,  8-(Ethoxycarbonyl)octyl 2-O,3-O-dibenzyl-4-O-benzoyl-β-L-fucopyranoside ,  8-(Ethoxycarbonyl)octyl 2-O-benzyl-3-O,4-O-isopropylidene-α-L-fucopyranoside ,  8-(Ethoxycarbonyl)octyl 2-O-benzyl-3-O,4-O-isopropylidene-β-L-fucopyranoside ,  8-(Ethoxycarbonyl)octyl 2-O-benzyl-3-O,4-O-dibenzoyl-β-L-fucopyranoside ,  9-Hydroxynonanoic acid ethyl ester ,  Decyl 2-O,3-O,4-O-tribenzyl-β-L-fucopyranoside ,  Decyl 2-O-benzyl-3-O,4-O-dibenzoyl-α-L-fucopyranoside ,  Phenyl 2-O,3-O-dibenzyl-4-O,6-O-dibenzoyl-1-thio-β-D-galactopyranoside ,  Methyl 2-O-[2-O-benzyl-3-O,4-O-dibenzoyl-α-L-fucopyranosyl]-3-O-benzyl-4-O,6-O-benzylidene-α-D-galactopyranoside

Terms in the title (5)： 溶媒 ,  誘起 ,  アノマー ,  ジアステレオ選択性 ,  切り替え