Art

J-GLOBAL ID：201102245180550634   Reference number：11A1620411

Ruthenium-catalyzed arylation of fluorinated aromatic ketones via ortho-selective carbon-fluorine bond cleavage

ortho-選択的炭素-フッ素結合開裂を経由するフッ素化芳香族ケトンのルテニウム接触アリール化

Author (5)： KAWAMOTO Keisuke (Dep. of Chemistry, Fac. of Sci. and Technol., Keio Univ., 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, JPN) ,  KOCHI Takuya (Dep. of Chemistry, Fac. of Sci. and Technol., Keio Univ., 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, JPN) ,  SATO Mitsuo (Dep. of Chemistry, Fac. of Sci. and Technol., Keio Univ., 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, JPN) ,  MIZUSHIMA Eiichiro (PRESTO, JST, 4-1-8 Honcho Kawaguchi, Saitama 332-0012, JPN) ,  KAKIUCHI Fumitoshi (Dep. of Chemistry, Fac. of Sci. and Technol., Keio Univ., 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 52  Issue： 44  Page： 5888-5890  Publication year： Nov. 02, 2011 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  catalytic reaction ,  ruthenium catalyst ,  ruthenium complex ,  carbonyl complex ,  phosphine complex ,  *arylation ,  *aromatic ketone ,  *aromatic fluorine compound ,  cleavage reaction ,  ester ,  organic boron acid ,  boron heterocyclic compound ,  oxygen heterocyclic compound ,  boronic acid ester ,  C-F bond
Semi thesaurus term： bond cleavage reaction ,  carbon-fluorine bond

JST classification (2)： Aromatic monocyclic ketones  (CF05170I) ,  Catalytic reactions in general  (CB06080F)

Substance index (15)： Methylpentafluorophenyl ketone ,  2′,3′,4′,5′-Tetrafluoroacetophenone ,  2',6'-Difluoroacetophenone ,  2′,6′-Diphenylacetophenone ,  2′-Acetyl-4,4′′-dimethyl-1,1′:3′,1′′-terbenzene ,  2′-Acetyl-4′,5′,6′-trifluoro-1,1′:3′,1′′-terbenzene ,  2′-Acetyl-4-methyl-1,1′:3′,1′′-terbenzene ,  2'-Fluoroacetophenone ,  2′-Fluoro-6′-(trifluoromethyl)acetophenone ,  2-p-Tolyl-5,5-dimethyl-1,3,2-dioxaborinane ,  2-Acetyl-3-(trifluoromethyl)biphenyl ,  2-Acetyl-3-[2-(trimethylsilyl)ethyl]biphenyl ,  2-Phenyl-5,5-dimethyl-2-bora-1,3-dioxane ,  8-Phenyltetralin-1-one ,  8-Fluorotetralin-1-one

Terms in the title (6)： 炭素-フッ素結合 ,  開裂 ,  フッ素 ,  芳香族ケトン ,  ルテニウム ,  アリール化