Art

J-GLOBAL ID：201102250514357958   Reference number：11A1502181

Asymmetric Induction Arising from Enantiomerically Enriched Carbon-13 Isotopomers and Highly Sensitive Chiral Discrimination by Asymmetric Autocatalysis

エナンチオマリッチの炭素13アイソトポマにより生じた不斉誘導と不斉自触媒作用による高選択的キラル認識

Author (4)： KAWASAKI Tsuneomi (Dep. of Applied Chemistry, Fac. of Sci., Tokyo Univ. of Sci.) ,  KAWASAKI Tsuneomi (Res. Inst. for Sci. and Technol., Tokyo Univ. of Sci.) ,  SOAI Kenso (Dep. of Applied Chemistry, Fac. of Sci., Tokyo Univ. of Sci.) ,  SOAI Kenso (Res. Inst. for Sci. and Technol., Tokyo Univ. of Sci.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 84  Issue： 9  Page： 879-892 (J-STAGE)  Publication year： 2011 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 解説  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *enantiomer ,  carbon 13 ,  *isotopomer ,  *asymmetric reaction ,  *autocatalysis ,  *selectivity ,  *molecular recognition ,  optical isomerism ,  nitrogen heterocyclic compound ,  alcohol ,  consecutive reaction ,  aldehyde ,  asymmetric synthesis ,  hydrogen ,  deuterium ,  amino acid ,  polystyrene ,  circularly polarized light ,  helicity ,  absolute configuration ,  crystal ,  aliphatic amine ,  aliphatic carboxylic acid
Semi thesaurus term： isotactic polystyrene ,  enantiomeric excess ,  chirality ,  chiral crystal ,  *chiral recognition ,  Pyrimidines ,  *asymmetric induction

JST classification (2)： Pyrimidines  (CF07103W) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (4)： Glycine ,  Diisopropylzinc ,  (S)-α-Isopropyl-2-(3,3-dimethyl-1-butynyl)-5-pyrimidinemethanol ,  (R)-α-Isopropyl-2-(3,3-dimethyl-1-butynyl)-5-pyrimidinemethanol

Reference (133)：

• 1) a) E. L. Eliel, S. H. Wilen, Stereochemistry of Organic Compounds, Wiley, New York, 1994.
•  b) K. Mislow, in Topics in Stereochemistry, ed. by S. E. Denmark, John Wiley & Sons, Inc., 1999, Vol. 22, p. 1. doi:10.1002/9780470147313.ch1.
• 2) L. Pasteur, Ann. Chim. Phys. 1848, 24, 442.
• 3) a) J. A. Le Bel, On the Relations which Exist between the Atomic Formulas of Organic Compounds and the Rotatory Power of Their Solutions in The Foundations of Stereochemistry, ed. by G. M. Richardson, New York, 1901, pp. 47–59.
•  b) J. H. Van’t Hoff, A Suggestion Looking to the Extension into Space of the Structural Formulas at Present Used in Chemistry, and a Note upon the Relationship between the Optical Activity and the Chemical Constitution of Organic Compounds in The Foundation of Stereochemistry, ed. by G. M. Richardson, New York, 1901, pp. 66–73.

Terms in the title (5)： 炭素13 ,  アイソトポマ ,  不斉誘導 ,  自触媒作用 ,  キラル認識