Art

J-GLOBAL ID：201102277047722740   Reference number：11A0295273

A Ruthenium-Catalyzed Hydrosilane-Induced Polymerization of 3-Alkyl-3-hydroxymethyloxetane Derivatives: Facile Access to Functionalized Polyoxetanes by Virtue of Organosilyl Groups

3-アルキル-3-ヒドロキシメチルオキセタン誘導体のルテニウム触媒によるヒドロシランによって誘起された重合:有機シリル基による官能化ポリオキセタンへの容易な接近

Author (8)： HARADA Nari-aki (Interdisciplinary Graduate School of Engineering Sciences, Kyushu Univ.) ,  YASUHARA Jushiro (Interdisciplinary Graduate School of Engineering Sciences, Kyushu Univ.) ,  MOTOYAMA Yukihiro (Inst. for Materials Chemistry and Engineering, Kyushu Univ.) ,  FUJIMURA Osamu (Organic Functional Material Res. Lab., Corporate Res. & Dev., UBE INDUSTRIES, LTD.) ,  TSUJI Tetsuro (Chemicals Dev. Center, Production & Technol. Div., UBE INDUSTRIES, LTD.) ,  TAKAHASHI Takeshi (Chemicals Dev. Center, Production & Technol. Div., UBE INDUSTRIES, LTD.) ,  TAKAHASHI Yoshiaki (Inst. for Materials Chemistry and Engineering, Kyushu Univ.) ,  NAGASHIMA Hideo (Inst. for Materials Chemistry and Engineering, Kyushu Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 84  Issue： 1  Page： 26-39 (J-STAGE)  Publication year： 2011 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *cyclic ether ,  *ruthenium catalyst ,  ruthenium complex ,  polynuclear complex ,  carbonyl complex ,  *ring-opening polymerization ,  *copolymerization ,  one-pot synthesis ,  dehydrogenation ,  *silylation ,  hydrolysis ,  side chain ,  functionalization ,  reaction mechanism ,  *polyether ,  acyl group ,  group(radical) ,  exchange reaction ,  glass transition point ,  melting point ,  alicyclic compound ,  conjugated diene ,  polynuclear aromatic hydrocarbon
Semi thesaurus term： *oxetanes ,  silyl group ,  trinuclear complex

JST classification (2)： Copolymerization  (CG04030D) ,  Reaction of polymers with low molecular weight compounds  (CG03020L)

Substance index (16)： Acenaphthylene ,  Phenyldimethylsilane ,  3-Methyloxetane-3-methanol ,  3-(Benzyloxymethyl)-3-methyloxetane ,  3-Methyl-3-(trimethylsiloxymethyl)oxetane ,  3-Methyl-3-[(dimethylphenylsilyloxy)methyl]oxetane ,  3-Methyl-3-(2,5,8-trioxanonane-1-yl)oxetane ,  3-(2,5,8,11-Tetraoxadodecane-1-yl)-3-methyloxetane ,  3-(2,2,3,3,3-Pentafluoropropoxymethyl)-3-methyloxetane ,  3-Ethyloxetane-3-methanol ,  3-(Benzyloxymethyl)-3-ethyloxetane ,  3-Ethyl-3-[(trimethylsilyloxy)methyl]oxetane ,  3-Ethyl-3-[(phenyldimethylsiloxy)methyl]oxetane ,  3-Ethyl-3-(2,5,8-trioxanonane-1-yl)oxetane ,  3-Ethyl-3-(2,5,8,11-tetraoxadodecane-1-yl)oxetane ,  3-Ethyl-3-(4,4,5,5,5-pentafluoro-2-oxapentane-1-yl)oxetane

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Terms in the title (10)： ヒドロキシメチル ,  オキセタン誘導体 ,  ルテニウム触媒 ,  ヒドロシラン ,  誘起 ,  重合 ,  有機シリル基 ,  官能化 ,  ポリオキセタン ,  接近