Art

J-GLOBAL ID：201102281882315400   Reference number：11A0942121

Synthesis of the ABC Ring System of Jiadifenin via Pd-Catalyzed Cyclizations

Pd触媒を用いた環化によるジアジフェニンのABC環系の合成

Author (7)： HARADA Kenichi (Tokushima Bunri Univ., Tokushima, JPN) ,  IMAI Akiko (Tokushima Bunri Univ., Tokushima, JPN) ,  UTO Kazuharu (Tokushima Bunri Univ., Tokushima, JPN) ,  CARTER Rich G. (Oregon State Univ., Oregon, USA) ,  KUBO Miwa (Tokushima Bunri Univ., Tokushima, JPN) ,  HIOKI Hideaki (Gunma Univ., Gunma, JPN) ,  FUKUYAMA Yoshiyasu (Tokushima Bunri Univ., Tokushima, JPN)
Material： Organic Letters  (Org Lett)
Volume： 13  Issue： 5  Page： 988-991  Publication year： Mar. 04, 2011 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  cyclization reaction ,  catalytic reaction ,  palladium complex ,  palladium catalyst ,  aliphatic ketone ,  aliphatic carboxylic acid ,  carboxylate(ester) ,  aliphatic alcohol ,  Archichlamydeae ,  *oxygen heterocyclic compound ,  *alicyclic compound ,  stereochemistry ,  *secondary metabolite
Semi thesaurus term： Honer-Wadsworth-Emmons reaction ,  Illicium jiadifengpi ,  Mizoroki-Heck reaction ,  Swern oxidation ,  Tsuji-Trost reaction ,  *Indans ,  *furans ,  部分合成

JST classification (4)： Condensed derivatives of furan  (CF07073M) ,  Indenes  (CF06030O) ,  Other natural substances of biological origin  (CF10090R) ,  Plant biochemistry  (EH01050J)

Substance index (17)： (3aR)-3aβ,4α-Dihydroxy-5aα-[3-(tert-butyldiphenylsiloxy)propyl]-8bβ-methyl-3,3aβ,4,5,5a,6,7,8b-octahydro-1H-indeno[4,5-c]furan-3-one ,  (3aR)-5aα-[3-(tert-Butyldiphenylsiloxy)propyl]-8bα-methyl-3,3aα,4,5,5a,6,7,8b-octahydro-1H-indeno[4,5-c]furan-3,4-dione ,  (3aS)-3aβ-[3-(tert-Butyldiphenylsiloxy)propyl]-5-oxo-8-methyl-1,2,3,3a,4,5-hexahydroazulene-6-carboxylic acid ethyl ester ,  (3aS)-5aα-[3-(tert-Butyldiphenylsiloxy)propyl]-8bβ-methyl-3,3aβ,4,5,5a,6,7,8b-octahydro-1H-indeno[4,5-c]furan-3,4-dione ,  (5S)-1-(Hydroxyacetyl)-5β-[3-(tert-butyldiphenylsiloxy)propyl]-5-[2-(triethylsiloxy)ethyl]-1-cyclopentene ,  (5S)-1-Acetyl-5β-[3-(tert-butyldiphenylsiloxy)propyl]-5-[2-(triethylsiloxy)ethyl]-1-cyclopentene ,  (5S)-5β-[3-(tert-Butyldiphenylsiloxy)propyl]-5-vinyl-1-cyclopentene-1-carboxylic acid ethyl ester ,  (5S)-N-Methyl-N-methoxy-5β-[3-(tert-butyldiphenylsiloxy)propyl]-5-[2-(triethylsiloxy)ethyl]-1-cyclopentene-1-carboxamide ,  2-Bromo-6-ethylidene-9-(tert-butyldiphenylsiloxy)-2-nonenoic acid ethyl ester ,  3-Oxo-4-[(1S)-1-[3-(tert-butyldiphenylsiloxy)propyl]-2-[(R)-2-oxo-4-methyl-1,3-dioxolane-4-yl]-2-cyclopentene-1α-yl]butanoic acid ethyl ester ,  3-Oxo-4-[(1S)-1-[3-(tert-butyldiphenylsiloxy)propyl]-2-[(S)-2-oxo-4-methyl-1,3-dioxolane-4-yl]-2-cyclopentene-1α-yl]butanoic acid ethyl ester ,  4-[(5S)-5β-[3-(tert-Butyldiphenylsiloxy)propyl]-5-(2-oxoethyl)-1-cyclopentene-1-yl]-4-methyl-1,3-dioxolane-2-one ,  4-[(5S)-5β-[3-(tert-Butyldiphenylsiloxy)propyl]-5-[2-(triethylsiloxy)ethyl]-1-cyclopentene-1-yl]-4-methyl-1,3-dioxolane-2-one ,  4-Ethylidene-7-(tert-butyldiphenylsiloxy)heptanal ,  4-Ethylideneheptane-1,7-diol ,  4-Oxopimelic acid diethyl ,  Jiadifenin

Terms in the title (5)： Pd触媒 ,  環化 ,  ジアジフェニン ,  ABC ,  環