Art

J-GLOBAL ID：201102283558008301   Reference number：11A0407681

Cis and trans radicals generated in helical poly(propargyl acetate)s prepared using a [Rh(norbornadiene)Cl]₂ catalyst

[Rh(ノルボルナジエン)Cl]₂触媒を用いて調製したヘリカルポリ(酢酸プロパルギル)で発生したcisおよびtransラジカル

Author (6)： YOSHIDA Yoshiaki (Dep. of Applied Chemistry, Graduate School of Engineering, Muroran Inst. of Technol., 27-1 Mizumoto-cho, Muroran ...) ,  MAWATARI Yasuteru (Dep. of Applied Chemistry, Graduate School of Engineering, Muroran Inst. of Technol., 27-1 Mizumoto-cho, Muroran ...) ,  SEKI Chigusa (Dep. of Applied Chemistry, Graduate School of Engineering, Muroran Inst. of Technol., 27-1 Mizumoto-cho, Muroran ...) ,  HIRAOKI Toshifumi (Dep. of Applied Physics, Graduate School of Engineering, Hokkaido Univ., Sapporo, Hokkaido 060-8628, JPN) ,  MATSUYAMA Haruo (Dep. of Applied Chemistry, Graduate School of Engineering, Muroran Inst. of Technol., 27-1 Mizumoto-cho, Muroran ...) ,  TABATA Masayoshi (Dep. of Applied Chemistry, Graduate School of Engineering, Muroran Inst. of Technol., 27-1 Mizumoto-cho, Muroran ...)
Material： Polymer
Volume： 52  Issue： 3  Page： 646-651  Publication year： Feb. 03, 2011 
JST Material Number： D0472B  ISSN： 0032-3861  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Thesaurus term： *stereospecific polymerization ,  rhodium complex ,  chloro complex ,  dinuclear complex ,  polymerization catalyst ,  rhodium catalyst ,  *polyacetylenes ,  ESR ,  computer simulation ,  *polymer radical ,  *isomerization ,  thermochemical reaction ,  molecular structure ,  stereoisomer ,  chemical synthesis ,  diene ,  cycloalkene ,  bridged compound
Semi thesaurus term： thermal isomerisation

JST classification (1)： Spectra of polymers  (CG02033O)

Substance index (2)： Norbornadiene ,  Propargyl acetate

Terms in the title (8)： Rh ,  ノルボルナジエン ,  Cl ,  触媒 ,  調製 ,  酢酸プロパルギル ,  CIS ,  ラジカル