Art

J-GLOBAL ID：201102290448533695   Reference number：11A0995666

Synthesis of novel fluorinated polymers: facile carbon-carbon bond formation aided by fluorine substituents

新規なフッ素化重合体の合成 : フッ素置換基により支援された簡便な炭素-炭素結合形成

Author (1)： NARITA Tadashi (Saitama Inst. of Technol., Fukaya, JPN)
Material： Polymer Journal
Volume： 43  Issue： 6  Page： 497-515  Publication year： Jun. 2011 
JST Material Number： F0612A  ISSN： 0032-3896  CODEN： POLJB8  Document type： Article
Article type： 文献レビュー  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *fluorine-containing polymer ,  *C-C bond ,  *anionic polymerization ,  *Michael reaction ,  radical polymerization ,  *polyaddition ,  addition reaction ,  polymer chain ,  vinyl compound ,  *aliphatic fluorine compound ,  reaction rate constant ,  reaction mechanism ,  polyalkyl methacrylate ,  polyalkyl acrylate ,  Lewis acid catalyst ,  Lewis base ,  polymerization catalyst ,  polymerization initiator ,  oligomer ,  polysilsesquioxane ,  organic-inorganic polymer hybrid ,  crown ether ,  azo compound ,  aliphatic nitrile ,  peroxide (organic) ,  aromatic carboxylic acid ,  Lewis base catalysis ,  polyhedral oligomeric silsesquioxane ,  dermatologic preparation
Semi thesaurus term： Michael addition ,  POSS(oligomer) ,  *carbon-carbon bond

JST classification (2)： Polymerization in general  (CG04010H) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (22)： 18-Crown-6 ,  AIBN ,  2,2,2-Trifluoroethyl acrylate ,  Cyanoacetic acid ethyl ,  Benzoyl peroxide ,  Hexafluoro-1,3-butadiene ,  Hexafluoro-2-butyne ,  2,2,3,3,4,4,4-Heptafluorobutyl=propenoate ,  Methacrylic acid 2,2,2-trifluoroethyl ester ,  α-(Trifluoromethyl)acrylic acid methyl ester ,  2-(Trifluoromethyl)acrylonitrile ,  α-(Trifluoromethyl)acrylic acid 2,2,2-trifluoroethyl ester ,  2-(Trifluoromethyl)acrylic acid 1-(trifluoromethyl)-2,2-difluoro-2-(tetrahydrofuran-2-yl)ethyl ester ,  2-(Heptadecafluorooctyl)ethyl=methacrylate ,  Acrylic acid 2,3,4,5,6-pentafluorobenzyl ester ,  Bis[2-(trifluoromethyl)acrylic acid]p-phenylene ester ,  2,2,3,3-Tetrafluoro-3-[1,2,2-trifluoro-1-(trifluoromethyl)-2-(trifluorovinyloxy)ethoxy]-1-propanol ,  Pentafluoroisopropenyl benzoate ,  Terephthalic acid bis(pentafluoroisopropenyl) ester ,  2-(Trifluoromethyl)-3-(tetrahydrofuran-2-yl)propanoic acid tert-butyl ester ,  2-(Trifluoromethyl)-3-(tetrahydro-2H-pyran-2-yl)propanoic acid tert-butyl ester ,  2-(Trifluoromethyl)-3-(1,4-dioxane-2-yl)propanoic acid tert-butyl ester

Reference (15)：

• WALL, L. A. ed. Fluoropolymers. 1972
• NARITA, T. Anionic polymerization of fluorinated vinyl monomers. Prog. Polym. Sci. 1999, 24, 1095-1148
• NARITA, T. On the polymerization reactivity of fluorinated vinyl monomers. Macromol. Rapid Commun. 2000, 21, 613-627
• CHAMBERS, R. D. ed. Organofluorine Chemistry-Fluorinated Alkenes and Reactive Intermediates. 1997
• NARITA, T. Stimulation on the addition reactivity of fluorinated vinyl monomers-facile carbon-carbon bond formation by the aid of fluorine substituents. J. Fluorine Chem. 2010, 131, 812-828

Terms in the title (5)： フッ素化重合体 ,  フッ素 ,  置換基 ,  支援 ,  炭素-炭素結合