Art

J-GLOBAL ID：201102293998767625   Reference number：11A1526877

Total synthesis of cucurbitoside-like phenolic glycosides by double fluorous and acyl mixture synthesis

二重フルオラスおよびアシル混合合成によるククルビトシド様フェノール性グリコシド類の全合成

Author (6)： KOJIMA Masaru (Niigata Univ. of Pharmacy and Applied Life Sciences, 265-1 Higashijima, Akiha-ku, Niigata 956-8603, JPN) ,  NAKAMURA Yutaka (Niigata Univ. of Pharmacy and Applied Life Sciences, 265-1 Higashijima, Akiha-ku, Niigata 956-8603, JPN) ,  KOMORI Kazuki (Niigata Univ. of Pharmacy and Applied Life Sciences, 265-1 Higashijima, Akiha-ku, Niigata 956-8603, JPN) ,  AKAI Shoji (Material and Life Chemistry, Fac. of Engineering, Kanagawa Univ., 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama ...) ,  SATO Ken-ichi (Material and Life Chemistry, Fac. of Engineering, Kanagawa Univ., 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama ...) ,  TAKEUCHI Seiji (Niigata Univ. of Pharmacy and Applied Life Sciences, 265-1 Higashijima, Akiha-ku, Niigata 956-8603, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 67  Issue： 43  Page： 8276-8292  Publication year： Oct. 28, 2011 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： total synthesis ,  *glycoside ,  Glycosylation ,  Acylation ,  *fluorous tag process
Semi thesaurus term： *fluorous synthesis

JST classification (1)： Glycosides  (CF10057O)

Substance index (14)： 4-(Benzyloxy)phenyl 3-O-[4-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)benzyl]-4-O,6-O-[(R)-benzylidene]-β-D-glucopyranoside ,  4-[2-(Benzyloxy)ethyl]phenyl 3-O-[4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyl)benzyl]-4-O,6-O-[(R)-benzylidene]-β-D-glucopyranoside ,  2,2,2-Trichloroacetimidic acid 2-O,3-O-benzylidene-5-O-benzoyl-D-apio-β-D-furanosyl ester ,  2,2,2-Trichloroacetimidic acid 2-O,3-O-benzylidene-5-O-(3-methylbutyryl)-D-apio-β-D-furanosyl ester ,  2,2,2-Trichloroacetimidic acid 2-O,3-O-benzylidene-5-O-[4-(benzyloxy)benzoyl]-D-apio-β-D-furanosyl ester ,  2,2,2-Trichloroacetimidic acid 2-O,3-O-benzylidene-5-O-(4-nitrobenzoyl)-D-apio-β-D-furanosyl ester ,  Seguinoside C ,  4-Hydroxyphenyl 2-O-[5-O-(3-methylbutyryl)-D-apio-β-D-furanosyl]-β-D-glucopyranoside ,  Seguinoside D ,  4-Hydroxyphenyl 6-O-[5-O-(4-aminobenzoyl)-D-apio-β-D-furanosyl]-β-D-glucopyranoside ,  Cucurbitoside A ,  4-(2-Hydroxyethyl)phenyl 2-O-[5-O-(3-methylbutyryl)-D-apio-β-D-furanosyl]-β-D-glucopyranoside ,  Cucurbitoside B ,  Cucurbitoside I

Terms in the title (3)： フェノール ,  グリコシド類 ,  全合成