Art

J-GLOBAL ID：201102294859717970   Reference number：11A0128689

Crystal Structures and Substitution Reactions of trans(O,S)-[Ru(bpy)Cl(dmso-S)₂(OH₂)]⁺ and Three Derivative Complexes, trans(L,S)-[Ru(bpy)Cl(dmso-S)₂(L)]⁺ (bpy: 2,2′-Bipyridine, dmso: Dimethyl Sulfoxide, L = dmso-O, MeOH, or MeCN)

trans(O,S)-[Ru(bpy)Cl(dmso-S)₂(OH₂)]⁺と三種類の誘導体錯体trans(L,S)-[Ru(bpy)Cl(dmso-S)₂(L)]⁺(bpy:2,2′-ビピリジン,dmso:ジメチルスルホキシド,L=dmso-O,MeOHまたはMeCN)の結晶構造と置換反応

Author (4)： TOYAMA Mari (Dep. of Applied Chemistry, Meiji Univ.) ,  IWAMATSU Shinobu (Dep. of Applied Chemistry, Meiji Univ.) ,  INOUE Ken-ichi (Dep. of Applied Chemistry, Meiji Univ.) ,  NAGAO Noriharu (Dep. of Applied Chemistry, Meiji Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 83  Issue： 12  Page： 1518-1527 (J-STAGE)  Publication year： 2010 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *ruthenium complex ,  amide complex ,  chloro complex ,  sulfoxide ,  aqua complex ,  solvation ,  solvate ,  chemical synthesis ,  *complex formation ,  *substitution reaction ,  ligand exchange ,  mutual transformation ,  *crystal structure ,  molecular structure ,  fluorophosphate ,  sulfonate ,  aliphatic fluorine compound ,  structural parameter ,  network structure ,  hydrogen bond ,  nitrogen heterocyclic compound ,  aliphatic nitrile ,  aliphatic compound ,  sulfonic acid ,  aliphatic alcohol
Semi thesaurus term： triflates

JST classification (2)： Platinum family element complexes  (CE01100E) ,  Crystal structure of complex of transition metals(excluding iron group)  (BK09030X)

Substance index (5)： 2,2'-Dipyridyl ,  Acetonitrile ,  Dimethyl sulfoxide ,  Trifluoromethanesulfonic acid anion ,  Methanol

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• 5) Md. K. Nazeeruddin, C. Klein, P. Liska, M. Grätzel, Coord. Chem. Rev. 2005, 249, 1460.

Terms in the title (10)： Ru ,  bpy ,  Cl ,  DMSO ,  誘導体 ,  錯体 ,  ビピリジン ,  ジメチルスルホキシド ,  結晶構造 ,  置換反応