Art

J-GLOBAL ID：201102299544941637   Reference number：11A1242132

Organocatalytic Tail-to-Tail Dimerization of Olefin: Umpolung of Methyl Methacrylate Mediated by N-Heterocyclic Carbene

オレフィンの有機触媒的テイルツーテイル二量化: 窒素複素環カルベンが介在したメタクリル酸メチルの極性変換

Author (7)： MATSUOKA Shin-ichi (Nagoya Inst. Technol., Nagoya, JPN) ,  OTA Yoshiya (Nagoya Inst. Technol., Nagoya, JPN) ,  WASHIO Atsushi (Nagoya Inst. Technol., Nagoya, JPN) ,  KATADA Akiho (Nagoya Inst. Technol., Nagoya, JPN) ,  ICHIOKA Kenji (Nagoya Inst. Technol., Nagoya, JPN) ,  TAKAGI Koji (Nagoya Inst. Technol., Nagoya, JPN) ,  SUZUKI Masato (Nagoya Inst. Technol., Nagoya, JPN)
Material： Organic Letters  (Org Lett)
Volume： 13  Issue： 14  Page： 3722-3725  Publication year： Jul. 15, 2011 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *transformation and conversion ,  *polarity ,  *dimerization ,  Electrospray Ionization Mass Spectrometry ,  reaction mechanism ,  deuteration ,  reaction intermediate ,  synthon ,  aliphatic carboxylic acid ,  olefin compound ,  unsaturated carboxylic acid ,  carboxylate (ester) ,  organic catalyst ,  *polarity conversion ,  fatty acid ester ,  *N-heterocyclic carbene
Semi thesaurus term： ESI-MS ,  *極性変換 ,  脂肪族カルボン酸エステル ,  *N-heterocyclic carbene

JST classification (2)： Photochemical reaction,radical reaction  (CF02090A) ,  Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P)

Substance index (13)： Methacrylic acid 2-(dimethylamino)ethyl ,  Methacrylic acid tert-butyl ,  Methacrylic acid methyl ,  Methacrylic acid benzyl ,  (1,3,4-Triphenyl-1H-1,2,4-triazole-5-ylidene)radical ,  (E)-2,5-Dimethyl-2-hexenedioic acid dimethyl ester ,  (E)-2,5-Dimethyl-2-hexenedioic acid di-tert-butyl ester ,  (E)-2,5-Dimethyl-2-hexenedioic acid dibenzyl ester ,  (E)-2,5-Dimethyl-2-hexenedioic acid bis[2-(dimethylamino)ethyl] ester ,  2-(²H₃)Methyl(3,3-²H₂)acrylic acid (²H₃)methyl ester ,  (E)-2,5-Di(²H₃)methyl(3,4,4,5-²H₄)-2-hexenedioic acid di(²H₃)methyl ester ,  (3,3-²H₂)Methacrylic acid methyl ester ,  (E)-2,5-Dimethyl(3,4,4,5-²H₄)-2-hexenedioic acid dimethyl ester

Terms in the title (5)： オレフィン ,  有機触媒 ,  窒素複素環カルベン ,  メタクリル酸メチル ,  極性変換