Art

J-GLOBAL ID：201202209848036432   Reference number：12A0538818

A new approach to the synthesis of 1-oxaspiro[4.n]alkanes and tetrahydrofurans by the 1,5-CH insertion reaction of magnesium carbenoids

マグネシウムカルベノイドの1,5-CH挿入反応による1-オキサスピロ[4.n]アルカンおよびテトラヒドロフラン類合成への新規アプローチ

Author (3)： SATOH Tsuyoshi (Graduate School of Chemical Sciences and Technol., Tokyo Univ. of Sci., Ichigaya-funagawara-machi 12, Shinjuku-ku ...) ,  YASOSHIMA Tsukasa (Graduate School of Chemical Sciences and Technol., Tokyo Univ. of Sci., Ichigaya-funagawara-machi 12, Shinjuku-ku ...) ,  MOMOCHI Hitoshi (Graduate School of Chemical Sciences and Technol., Tokyo Univ. of Sci., Ichigaya-funagawara-machi 12, Shinjuku-ku ...)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 53  Issue： 16  Page： 2074-2077  Publication year： Apr. 18, 2012 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： spiro-compound ,  *oxygen heterocyclic compound ,  insertion reaction ,  organomagnesium compound ,  carbene ,  *alicyclic ketone ,  acetal ,  Cyclohexanes
Semi thesaurus term： Cyclohexanes

JST classification (2)： Cyclohexanes  (CF04050W) ,  Furans  (CF07072V)

Substance index (15)： 8-[2-Chloro-2-(p-tolylsulfinyl)ethyl]-8-(benzyloxy)-1,4-dioxaspiro[4.5]decane ,  10-Phenyl-1,4,9-trioxadispiro[4.2.4.2]tetradecane ,  8-(2-Chloroethyl)-8-(benzyloxy)-1,4-dioxaspiro[4.5]decane ,  1,4-Dioxaspiro(4.5)decane-8-one ,  1,4,9-Trioxadispiro[4.2.4.2]tetradecane ,  10-Methyl-1,4,9-trioxadispiro[4.2.4.2]tetradecane ,  6-Phenyl-5-oxaspiro[3.4]octane ,  2-Phenyl-1-oxaspiro[4.4]nonane ,  2-Phenyl-1-oxaspiro[4.5]decane ,  2-Phenyl-1-oxaspiro[4.7]dodecane ,  2-Phenyl-1-oxaspiro[4.14]nonadecane ,  2,2-Dimethyl-5-phenyltetrahydrofuran ,  2,2-Diphenethyl-5-phenyltetrahydrofuran ,  2,2,5-Triphenyltetrahydrofuran ,  10-Methyl-1,4-dioxadispiro[4.2.4.2]tetradecane

Terms in the title (5)： マグネシウムカルベノイド ,  CH ,  挿入反応 ,  アルカン ,  テトラヒドロフラン類