Art

J-GLOBAL ID：201202217295486100   Reference number：12A1500350

Highly regioselective hydroiodination of terminal alkynes and silylalkynes with iodine and phosphorus reagents leading to internal iodoalkenes

内部ヨードアルケンを生成するヨウ素とリン試薬による末端アルキンおよびシリルアルキンの高位置選択的ヒドロヨウ素化

Author (5)： KAWAGUCHI Shin-ichi (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture Univ., 1-1 Gakuen-cho, Nakaku, Sakai ...) ,  MASUNO Haruna (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture Univ., 1-1 Gakuen-cho, Nakaku, Sakai ...) ,  SONODA Motohiro (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture Univ., 1-1 Gakuen-cho, Nakaku, Sakai ...) ,  NOMOTO Akihiro (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture Univ., 1-1 Gakuen-cho, Nakaku, Sakai ...) ,  OGAWA Akiya (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture Univ., 1-1 Gakuen-cho, Nakaku, Sakai ...)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 68  Issue： 47  Page： 9818-9825  Publication year： Nov. 25, 2012 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： addition reaction ,  regiospecific reaction ,  *alkyne ,  iodine ,  *organosilicon compound ,  reaction mechanism ,  aromatic hydrocarbon ,  acetylenic compound
Semi thesaurus term： *ヒドロヨウ素化

JST classification (2)： Organosilicon compounds  (CF08030C) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (21)： 1-Octyne ,  1-Dodecyne ,  (1-Iodovinyl)benzene ,  Phenylacetylene ,  Diphenylphosphine oxide ,  Trimethyl(phenylethynyl)silane ,  2-Iodo-1-octene ,  2-Iodo-1-dodecene ,  1-Octynyldiphenylphosphine oxide ,  [(Z)-2-Iodo-1-octenyl]diphenylphosphine oxide ,  (Z)-1-Phenyl-3-iodo-2-nonene-1-one ,  α-Iodo-4-pentylstyrene ,  α-Iodo-4-bromostyrene ,  1-(1-Iodovinyl)-4-(trifluoromethyl)benzene ,  4-(1-Iodovinyl)benzonitrile ,  1-(Trimethylsilyl)-1-octyne ,  1-Dodecynyltrimethylsilane ,  α-Iodo-4-methylstyrene ,  α-Iodo-4-methoxystyrene ,  Dimethylphenyl(1-octynyl)silane ,  1-(Triethoxysilyl)-1-octyne

Terms in the title (7)： アルケン ,  ヨウ素 ,  リン ,  試薬 ,  末端アルキン ,  位置選択 ,  ヨウ素化