Art

J-GLOBAL ID：201202231083504438   Reference number：12A1603872

Cinchona alkaloids induce asymmetry in the insertion reaction of thermally generated carbenes into N-H bonds

熱的に生成したカルベンのN-H結合への挿入反応におけるシンコナアルカロイド誘導不斉

Author (5)： SAITO Hiroaki (School of Pharmacy, Nihon Univ., 7-1-7, Narashinodai, Funabashi, Chiba 274-8555, JPN) ,  MORITA Daisuke (School of Pharmacy, Nihon Univ., 7-1-7, Narashinodai, Funabashi, Chiba 274-8555, JPN) ,  UCHIYAMA Taketo (School of Pharmacy, Nihon Univ., 7-1-7, Narashinodai, Funabashi, Chiba 274-8555, JPN) ,  MIYAKE Muneharu (School of Pharmacy, Nihon Univ., 7-1-7, Narashinodai, Funabashi, Chiba 274-8555, JPN) ,  MIYAIRI Shinichi (School of Pharmacy, Nihon Univ., 7-1-7, Narashinodai, Funabashi, Chiba 274-8555, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 53  Issue： 49  Page： 6662-6664  Publication year： Dec. 05, 2012 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *insertion reaction ,  amino group ,  chemical bond ,  *carbene ,  *quinoline alkaloid ,  asymmetric reaction ,  catalyst ,  organic compound ,  asymmetric synthesis ,  thermal decomposition ,  ammonium ylide ,  aromatic amine ,  primary amine
Semi thesaurus term： N-H bond ,  *chinchona alkaloid ,  asymmetric induction ,  organocatalyst

JST classification (2)： Aromatic monocyclic carboxylic esters,carboxylic anhydrides,acid halides  (CF05190E) ,  Other catalysts  (CB06123Z)

Substance index (13)： Aniline ,  Dihydrocinchonine ,  2-Phenyl-2-diazoacetic acid ethyl ester ,  Methyl phenyldiazoacetate ,  N-Phenyl-D-phenylglycine methyl ester ,  (R)-Anilinophenylacetic acid tert-butyl ester ,  (R)-Anilinophenylacetic acid ethyl ester ,  (R)-(4-Fluoroanilino)phenylacetic acid ethyl ester ,  (R)-(4-Chloroanilino)phenylacetic acid ethyl ester ,  (R)-(4-Bromoanilino)phenylacetic acid ethyl ester ,  (R)-[4-(Trifluoromethyl)anilino]phenylacetic acid ethyl ester ,  (R)-(4-Methoxyanilino)phenylacetic acid ethyl ester ,  (R)-(4-tert-Butylanilino)phenylacetic acid ethyl ester

Terms in the title (5)： カルベン ,  N-H結合 ,  挿入反応 ,  シンコナアルカロイド ,  誘導