Art

J-GLOBAL ID：201202278787898136   Reference number：12A1094128

Enantio- and diastereoselective hetero-Diels-Alder reactions between 2-aza-3-silyloxy-1,3-butadienes and aldehydes catalyzed by chiral dirhodium(II) carboxamidates

2-アザ-3-シリルオキシ-1,3-ブタジエン類とアルデヒド類との間のキラルジロジウム(II)カルボキシアミダート類を触媒とするエナンチオ-並びにジアステレオ選択的ヘテロDiels-Alder反応

Author (5)： WATANABE Yudai (Hokkaido Univ., Sapporo, JPN) ,  WASHIO Takuya (Hokkaido Univ., Sapporo, JPN) ,  KRISHNAMURTHI Janagiraman (Hokkaido Univ., Sapporo, JPN) ,  ANADA Masahiro (Hokkaido Univ., Sapporo, JPN) ,  HASHIMOTO Shunichi (Hokkaido Univ., Sapporo, JPN)
Material： Chemical Communications  (ChemComm)
Volume： 48  Issue： 55  Page： 6969-6971  Publication year： Jul. 14, 2012 
JST Material Number： D0376B  ISSN： 1359-7345  CODEN： CHCOFS  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *Diels-Alder reaction ,  *asymmetric synthesis ,  stereoselectivity ,  *diene ,  *rhodium catalyst ,  rhodium complex ,  catalytic reaction ,  *asymmetric catalyst ,  chiral ligand ,  amide acid ,  carbamate ,  *aromatic aldehyde ,  aliphatic aldehyde ,  organosilicon compound ,  ether ,  enol ether ,  reaction mechanism ,  acid imide ,  nitrogen heterocyclic compound ,  dinuclear complex ,  imine ,  diastereoselectivity ,  silyl ether ,  *hetero Diels-Alder reaction ,  Piperidines
Semi thesaurus term： Piperidines

JST classification (8)： Platinum family element complexes  (CE01100E) ,  Oxazines  (CF07100X) ,  Aromatic monocyclic aldehydes  (CF05160X) ,  Aliphatic aldehydes  (CF03180F) ,  Alkenes  (CF03030T) ,  Pyridines  (CF07095Q) ,  Condensed derivatives of pyrroles  (CF07077C) ,  Naphthalenes  (CF06020D)

Substance index (10)： 4-(Trifluoromethyl)benzaldehyde ,  (Benzyloxy)acetaldehyde ,  Benzaldehyde ,  2β,6β-Diphenyltetrahydro-4H-1,3-oxazine-4-one ,  N-Benzylidene-1-(tert-butyldimethylsiloxy)etheneamine ,  N-[(3S)-2-Oxo-3-piperidinyl]naphthalene-2,3-dicarbimide ,  3-Phenylpropynal ,  2β-Phenyl-6β-[4-(trifluoromethyl)phenyl]tetrahydro-4H-1,3-oxazine-4-one ,  2β-Phenyl-6β-(phenylethynyl)tetrahydro-4H-1,3-oxazine-4-one ,  2β-Phenyl-6β-(benzyloxymethyl)tetrahydro-4H-1,3-oxazine-4-one

Terms in the title (5)： ブタジエン類 ,  アルデヒド類 ,  触媒 ,  ジアステレオ選択 ,  ヘテロDiels-Alder反応