Art

J-GLOBAL ID：201302216119874081   Reference number：13A1763337

Activation of Dioxygen in an Aqueous System of [Fe^IIITMPyP]-MBTH-O₂ to Form Peroxide and Azine from MBTH: Reactivity of Superoxohemin ([Fe^IIITMPyP-OO] ) and Peroxohemin ([Fe^IIITMPyP-OO]^-)

MBTHからペルオキシドとアジンを生成するための[Fe^IIITMPyP]-MBTH-O₂の水性系における二原子酸素の活性化 スーパオキソヘミン([Fe^IIITMPyP-OO]^・)及びペルオキソヘミン([Fe^IIITMPyP-OO]^-)の反応性

Author (5)： NAKANO Taku (Dep. of Chemistry, Fac. of Sciences, Toho Univ.) ,  NAKANO Taku (Dep. of Pharmaceutical Sciences, Univ. of Toyama) ,  KAKUDA Hiroko (Dep. of Pharmaceutical Sciences, Univ. of Toyama) ,  SHINODA Hiroyuki (Dep. of Pharmaceutical Sciences, Univ. of Toyama) ,  MORIYAMA Hiroshi (Dep. of Chemistry, Fac. of Sciences, Toho Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 86  Issue： 5  Page： 620-627 (J-STAGE)  Publication year： 2013 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  *sulfur heterocyclic compound ,  *hydrazone ,  peroxide(organic) ,  vic-polynitrogen compound ,  aromatic compound ,  porphyrin complex ,  bridged compound ,  macrocyclic compound ,  *oxygen ,  diatomic molecule ,  *activation ,  *superoxo complex ,  *hemin ,  *peroxo complex ,  *reactivity ,  heme ,  water solubility ,  chloro complex ,  reducing agent ,  superoxide anion radical ,  hydrogen peroxide ,  oxidizing agent ,  reaction product ,  reaction intermediate ,  superoxide dismutase ,  catalase ,  superoxide ,  oxo complex ,  anaerobic ,  hydropolyoxide ,  aliphatic compound ,  ketone ,  NADPH oxidase ,  cytochrome P450 ,  nitric oxide synthase ,  reaction mechanism ,  coenzyme ,  adenine nucleotide ,  nicotinamide mononucleotide
Semi thesaurus term： NO synthase ,  superoxide ,  dioxygen ,  *benzothiazole derivative

JST classification (3)： Thiazoles,isothiazoles  (CF07081P) ,  Iron complex  (CE01091H) ,  Oxidation,reduction  (CF02060T)

Substance index (7)： MBTH ,  NADPH ,  tert-Butyl hydroperoxide ,  meso-Tetra(N-methyl-4-pyridyl)porphine ,  2,2′-Azinobis(3-methyl-2,3-dihydrobenzothiazole) ,  2,2′-Peroxybis(3-methyl-2,3-dihydrobenzothiazole) ,  3-Methylbenzothiazoline-2-one

Reference (38)：

• 1) R. Lemberg, J. W. Legge, W. H. Lockwood, Nature 1938, 142, 148.
• 2) T. D. H. Bugg, Tetrahedron 2003, 59, 7075.
• 3) N. V. Chandrasekharan, D. L. Simmons, Genome Biol. 2004, 5, 241.
• 4) D. C. Zimmerman, B. A. Vick, Lipids 1970, 5, 392.
• 5) J. K. Hurst, in The Activation of Dioxygen and Homogeneous Catalytic Oxidation, ed. by D. H. R. Barton, A. E. Martell, D. T. Sawyer, Plenum, New York, 1993, pp. 267–286. doi:10.1007/978-1-4615-3000-8_20.

Terms in the title (7)： MBTH ,  ペルオキシド ,  アジン ,  O2 ,  二原子酸素 ,  活性化 ,  反応性