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J-GLOBAL ID：201302227226865330   Reference number：13A0040925

CHIRAL PRIMARY AMINO SILYL ETHER ORGANOCATALYST FOR THE ENANTIOSELECTIVE DIELS-ALDER REACTION OF 1,2-DIHYDROPYRIDINES WITH AlDEHYDES

1,2-ジヒドロピリジンとアルデヒドのエナンチオ選択的Diels-Alder反応のためのキラルアミノシリルエーテル有機触媒

Author (12)： SAKUTA Yuki (Muroran Inst. of Technol., Muroran, JPN) ,  KOHARI Yoshihito (Muroran Inst. of Technol., Muroran, JPN) ,  ROMAULI HUTABARAT N. D. M. (Muroran Inst. of Technol., Muroran, JPN) ,  UWAI Koji (Muroran Inst. of Technol., Muroran, JPN) ,  KWON Eunsang (Tohoku Univ., Sendai, JPN) ,  OKUYAMA Yuko (Tohoku Pharmaceutical Univ., Sendai, JPN) ,  SEKI Chigusa (Muroran Inst. of Technol., Muroran, JPN) ,  MATSUYAMA Haruo (Muroran Inst. of Technol., Muroran, JPN) ,  TAKANO Nobuhiro (Muroran Inst. of Technol., Muroran, JPN) ,  TOKIWA Michio (Tokiwakai Group, Iwaki, JPN) ,  TAKESHITA Mitsuhiro (Tokiwakai Group, Iwaki, JPN) ,  NAKANO Hiroto (Muroran Inst. of Technol., Muroran, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 86  Issue： 2  Page： 1379-1389  Publication year： Dec. 31, 2012 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Diels-Alder reaction ,  stereoselectivity ,  bridged compound ,  *nitrogen heterocyclic compound ,  aldehyde ,  reaction mechanism ,  *aminoalcohol ,  silylation ,  aliphatic aldehyde ,  unsaturated aldehyde ,  vinyl compound ,  carboxylic acid
Semi thesaurus term： enantioselectivity ,  Quinuclidines ,  *silyl ether ,  *organocatalyst ,  organocatalysis

JST classification (2)： Other condensed derivatives of pyridine  (CF07097Y) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (17)： 1,2-Dihydropyridine ,  Acrolein ,  Isonicotinic acid ,  Hayashi-Joergensen catalyst ,  (2S)-1-(Trimethylsiloxy)-1,1-diphenyl-3,3-dimethylbutane-2-amine ,  [(S)-1,1-Diphenyl-2-amino-3,3-dimethylbutyl](trimethylsilyl) ether・trifluoroacetic acid ,  Pyridine-1(2H)-carboxylic acid phenyl ester ,  1-(Benzyloxycarbonyl)-1,2-dihydropyridine ,  (1α,4α)-6α-Formyl-2-azabicyclo[2.2.2]octa-7-ene-2-carboxylic acid phenyl ester ,  (1β,4β)-7β-Formyl-2-azabicyclo[2.2.2]octa-5-ene-2-carboxylic acid benzyl ester ,  (1β,4β,7R)-7-Formyl-2-azabicyclo[2.2.2]octa-5-ene-2-carboxylic acid phenyl ester ,  (1β,4β,7R)-7-Formyl-2-azabicyclo[2.2.2]octa-5-ene-2-carboxylic acid benzyl ester ,  3-Formylacrylic acid methyl ester ,  (1α,4α)-6α-Formyl-2-azabicyclo[2.2.2]octa-7-ene-2,5β-dicarboxylic acid 2-phenyl 5-methyl ester ,  (1α,4α)-6α-Formyl-2-azabicyclo[2.2.2]octa-7-ene-2,5β-dicarboxylic acid 2-benzyl 5-methyl ester ,  (1α,4α)-6α-(Hydroxymethyl)-2-azabicyclo[2.2.2]octa-7-ene-2,5β-dicarboxylic acid 2-phenyl 5-methyl ester ,  (1α,4α)-6α-(Hydroxymethyl)-2-azabicyclo[2.2.2]octa-7-ene-2,5β-dicarboxylic acid 2-benzyl 5-methyl ester

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Terms in the title (4)： ジヒドロピリジン ,  アルデヒド ,  Diels-Alder反応 ,  有機触媒