Art

J-GLOBAL ID：201302228130955016   Reference number：13A0353335

Stereoselective synthesis of zoanthenol ABC-ring by radical strategy

ラジカル戦略によるゾアンテノールABC環の立体選択的合成

Author (5)： YAMASHITA Shuji (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  SUDA Naoki (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  HAYASHI Yujiro (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  HIRAMA Masahiro (Dep. of Chemistry, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN) ,  HIRAMA Masahiro (Res. and Analytical Center for Giant Molecules, Graduate School of Sci., Tohoku Univ., Sendai 980-8578, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 54  Issue： 11  Page： 1389-1391  Publication year： Mar. 13, 2013 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *asymmetric synthesis ,  isolation(separation) ,  radical reaction ,  functionalization ,  Zoantharia ,  *alkaloid ,  *phenolic compound ,  marine animal ,  biological sample analysis ,  marine natural product
Semi thesaurus term： Zoanthus sp.

JST classification (2)： Alkaloids  (CF10030D) ,  Aromatic monocyclic phenols and polyphenols  (CF05090V)

Substance index (5)： Zoanthenol ,  (E)-3-Oxo-2,6-dimethyl-9-(2-methoxy-4-methylphenyl)-6-nonenoic acid ethyl ester ,  3-[2-[(6aS)-4-Methoxy-2,7,7aα,9aα-tetramethyl-5,6,6aβ,7,7a,8aα,9,9a-octahydrophenanthro[2,3-b]oxirene-7α-yl]ethoxy]acrylic acid ethyl ester ,  3-[(1S)-1α-(2-Hydroxyethyl)-3β-hydroxy-8-methoxy-1,2,4aα,6-tetramethyl-1,2,3,4,4a,9,10,10aβ-octahydrophenanthrene-2α-yl]acrylic acid ethyl ester ,  (1S)-1α-[2-(tert-Butyldimethylsiloxy)ethyl]-3β-(tert-butyldimethylsiloxy)-10β-hydroxy-8-methoxy-1,2,4aα,6-tetramethyl-1,2,3,4,4a,9,10,10aβ-octahydrophenanthrene-2α-propanoic acid ethyl ester

Terms in the title (6)： ラジカル ,  戦略 ,  ゾアンテノール ,  ABC ,  環 ,  立体選択的合成